Home
Class 12
CHEMISTRY
d(x2),d(yz) and d(zx) orbitals have ener...

`d_(x2),d_(yz)` and `d_(zx)` orbitals have________ energies and are collectively termed_________ or __________or___________orbitals .

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question about the energies of the \(d_{x^2}\), \(d_{yz}\), and \(d_{zx}\) orbitals, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Orbitals**: The orbitals in question are \(d_{x^2}\), \(d_{yz}\), and \(d_{zx}\). These orbitals are part of the d-orbital set in transition metal complexes. 2. **Understand Crystal Field Theory**: According to Crystal Field Theory (CFT), the five d-orbitals split into two groups in the presence of ligands. These groups are known as the \(t_{2g}\) and \(e_g\) sets. 3. **Classify the Orbitals**: - The orbitals \(d_{yz}\), \(d_{zx}\), and \(d_{xy}\) belong to the \(t_{2g}\) set and have the same energy level due to their symmetrical arrangement in the crystal field. - The orbitals \(d_{x^2}\) and \(d_{z^2}\) belong to the \(e_g\) set and have higher energy compared to \(t_{2g}\) orbitals. 4. **Determine Energy Levels**: Since \(d_{yz}\) and \(d_{zx}\) are part of the \(t_{2g}\) set, they have the same energy. Therefore, we can say that \(d_{x^2}\), \(d_{yz}\), and \(d_{zx}\) orbitals have equal energies. 5. **Collective Term for the Orbitals**: The orbitals \(d_{yz}\) and \(d_{zx}\) are collectively termed as \(t_{2g}\) orbitals. 6. **Final Answer**: - The \(d_{x^2}\), \(d_{yz}\), and \(d_{zx}\) orbitals have **equal energies** and are collectively termed **\(t_{2g}\)** or **non-axial** or **d-orbitals**. ### Final Answer: The \(d_{x^2}\), \(d_{yz}\), and \(d_{zx}\) orbitals have **equal energies** and are collectively termed **\(t_{2g}\)** or **non-axial** or **d-orbitals**.
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises True/False|14 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Linked Comprehension)|5 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer (Hybridisation , Vbt , Cft And Application)|13 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|23 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos

Similar Questions

Explore conceptually related problems

d_(z^(2)) -orbital has:

4s orbitals has less energy than 3d orbital

4s orbitals has less energy than 3d orbital

d_(xy),d_(yz) and d_(xz) orbitals is involved in which of the following hybridisation?

d orbitals are five fold degenerate and are speclled as …………….

for 3d_(z^2) orbital the value of l and m respectively are

d_(x^2-y^2) and d_(z^2) orbitals is involved in which of the foollowing hybridisation?

No of e^(Θ) in 2d orbital are :-

The 3d-orbitals having electron density in all the three axes is

The hybrid orbital having only 20% d character

CENGAGE CHEMISTRY ENGLISH-COORDINATION COMPOUNDS-Exercises Fill The Blanks
  1. The magnitude of stability constant gives an indication of the stabili...

    Text Solution

    |

  2. Under the influence of strong the ligands the electrons can be forceda...

    Text Solution

    |

  3. d(x2),d(yz) and d(zx) orbitals have energies and are collectively term...

    Text Solution

    |

  4. d(xy),d(yz) and d(zx) orbitals have energies and are collectively term...

    Text Solution

    |

  5. Organometallic compounds are those compounds which contain one or more...

    Text Solution

    |

  6. d^(2) sp^(3) hybridisation of the central atom gives the orbital compl...

    Text Solution

    |

  7. Wilkinson's catalyst, unsed as a catalyst in the hydrogenation of alke...

    Text Solution

    |

  8. Recently the platinum complex known as cisplatin has been found in the...

    Text Solution

    |

  9. Ziegker-Natta catalyst, used as a catalyst for the low temperature pol...

    Text Solution

    |

  10. Zeisse's-salt Ferrocene and Dibenzene chromium are the example of bond...

    Text Solution

    |

  11. Calcium dihydrogen salt of EDTA is used as an antidote for the poisoni...

    Text Solution

    |

  12. [Co(NH(3))(5)SO(4)]Br and [Co(NH(3))(5)Br]SO(4) shown isomerism .

    Text Solution

    |

  13. According to valence bond theory the geometry of [Ni(CO)(4)] is .

    Text Solution

    |

  14. K(4)Fe(CO)(6) is considered to a be a complex but potash alum isand bl...

    Text Solution

    |

  15. Grignard reagent is a organometallic compound .

    Text Solution

    |

  16. [Co(NH(3))(6)]^(3+) is diamagnetic while [CoF(6)]^(3-) is .

    Text Solution

    |

  17. [ptabcd]^(n+-) hasshape and has geometrical isomers .

    Text Solution

    |

  18. Geomerical isomerism is not observed in complexes of coordination numb...

    Text Solution

    |

  19. Trans form of [M(A A)(2)a(2)]^(n+) complex does not show isomerism .

    Text Solution

    |

  20. Dimethylglyoxime is used from the gravimetic estimation of ion .

    Text Solution

    |