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[Co(NH(3))(5)SO(4)]Br and [Co(NH(3))(5)B...

`[Co(NH_(3))_(5)SO_(4)]Br` and `[Co(NH_(3))_(5)Br]SO_(4)` shown _________isomerism .

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Ionisation
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[Co(NH_(3))_(5)NO_(2)]SO_(4) shows

A mixture x containing 0.02 mol of [Co(NH_(3))_(5) SO_(4)]Br and 0.02 mol of [Co(NH_(3))_(5)Br]SO_(4) was prepared in 2 L of solution. 1 L of mixture X + excess AgNO_(3) rarr Y 1 L of mixture X + excess BaCl_(2) rarr Z The number of moles of Y and Z are

A 2 lit solution contains 0.04 mol of each of [CO(NH_(3))_(5)SO_(4)]Br and [CO(NH_(3))_(5)Br]SO_(4) . To 1 lit of this solution, excess of AgNO_(3) is added. To the remaining solution of excess of BaCl_(2) is added. The amounts of precipitated salts, respectively, are

Give evidence that [Co(NH_3)_5Cl]SO_4 and [Co(NH_3)_5SO_4]Cl are ionisation isomers.

What type of isomerism exists in the following pairs of complexes ? (i) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5) SO_(4) ] NO_(3) (ii) [Co(en)(H_(2)O)_(2) Cl_(2)] Cl and [Co(en) (H_(2)O) Cl_(3) ] H_(2)O

coordination compounds often show various types of isomerism. The isomerism can be categorized in two main types (a) structural isomerism (b) stereo or space isomerism Structural isomerism arises due to the difference in structures of coordination-sempounds while stereo or space isomerism arises on account of the different positions and arrangements of ligands (atoms or groups) in space around the metal lonStructural isomerism can be classified in following types (i) tonization isomers- which give different ions in solution, e.g. [CoBr(NH_(3))_(5)]]SO_(4) and [Co(SO_(4))_(5)(NH_(3))_(5)]Br Hydrate isomers which differ in H_(2)O as ligand or as hydration, e.g. [Cr(H_(2)O)_(5)]CI_(2)(H_(2)O)]Cl_(2).H_(2)O[CrCl_(2)(H_(2)O)]CI.2H_(2)O (iii) Linkage isomers, which differ in atom linked to 'metal atom, e.g. [CO(NO_(2))(NH_(3))_(5)]^(2+) and CO(ONO)(NH_(3))_(6)]^(2+) Coordination isomers- which involve interchange of ligands, e.g. [Co(NH_(3))_(6)] [Cr(CN)_(6)] and [Cr(NH_(3))_(6)] [Co(CN)_(6)] (v) Coordination position isomerism-which arises in the bridged complexes due to the difference in the attachment of ligands with the metal atoms QThe pair [CO(NH_(3))_(5)NO_(3)]SO_(4) and [CO(NH_(3))SO_(4)]NO_(3) will exhibit

Give evidence that [Co(NH_3)_5Cl]SO_4 and [Co(NH_3)_5 SO_4]CL are ionization isomers.

[Cr(NH_(3))_(5)NO_(2)]SO_(4) and [Cr(NH_(3))_(5)ONO]SO_(4) are related to each other as: .

Consider the following reaction and statements: [Co(NH_(3))_(4)Br_2]^(+)+Br^(-) to [Co(NH_(3))_(3)Br_3]+NH_(3) (I) Two isomers are produced if the reactant complex ion is a cis-isomer. (II) Two isomers are produced if the reactant complex ion is a tran-isomer. (III) Only one isomers is produced if the reactant complex ion is a tran-isomer. (IV) Only one isomers is produced if the reactant complex ion is a cis-isomer. The correct statements are :

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  5. Calcium dihydrogen salt of EDTA is used as an antidote for the poisoni...

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  6. [Co(NH(3))(5)SO(4)]Br and [Co(NH(3))(5)Br]SO(4) shown isomerism .

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  7. According to valence bond theory the geometry of [Ni(CO)(4)] is .

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  8. K(4)Fe(CO)(6) is considered to a be a complex but potash alum isand bl...

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  9. Grignard reagent is a organometallic compound .

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  10. [Co(NH(3))(6)]^(3+) is diamagnetic while [CoF(6)]^(3-) is .

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  11. [ptabcd]^(n+-) hasshape and has geometrical isomers .

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  12. Geomerical isomerism is not observed in complexes of coordination numb...

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  13. Trans form of [M(A A)(2)a(2)]^(n+) complex does not show isomerism .

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  14. Dimethylglyoxime is used from the gravimetic estimation of ion .

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  15. EDTA is used as a complexing agent in estimation of metal ions like Ca...

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  16. Potassium hexanitrocobaltate III K(3)[Co(NO(2))(6)] is called .

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  17. Haemoglobin is a complex of chlorophyll is a complex of and vitamin B(...

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  18. Organo arsenic compounds are used as remedy for .

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  19. is used to prevent the infection of young plants .

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  20. is an important anti knock compound added to petrol used in internal c...

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