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Which of the following statement(s) is(a...

Which of the following statement(s) is(are) correct ?

A

Soluble sulphide gives black precipitate with `AgNO_(3)` solution which is soluble in hot dilute nitric acid

B

Soluble sulphide produces a yellow precipitate with a susponsion of a cadmium carbonate.

C

Sulphide ion reacts with sodium nitroprusside and gives a purple colouration

D

Free `H_(2)S` gasa reacts with form preipitate with tertradrooxide plumbates (II) solution

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the statements regarding soluble sulfides and their reactions are correct, we will analyze each statement step by step. ### Step-by-Step Solution: 1. **Statement A: Soluble sulfide gives black precipitate with silver nitrate solution which is soluble in hot dilute nitric acid.** - When soluble sulfides (like sodium sulfide, Na2S) react with silver nitrate (AgNO3), they form a black precipitate of silver sulfide (Ag2S). - The reaction can be represented as: \[ 2 \text{Ag}^+ + \text{S}^{2-} \rightarrow \text{Ag}_2\text{S} \downarrow \] - This black precipitate of silver sulfide is soluble in hot dilute nitric acid, leading to the formation of silver nitrate, sulfur, nitric oxide, and water: \[ \text{Ag}_2\text{S} + 4 \text{HNO}_3 \rightarrow 2 \text{AgNO}_3 + \text{S} + 2 \text{NO} + 2 \text{H}_2\text{O} \] - **Conclusion:** Statement A is correct. 2. **Statement B: Soluble sulfide produces a yellow precipitate with suspension of cadmium carbonate.** - When soluble sulfides react with cadmium ions (from cadmium carbonate), a yellow precipitate of cadmium sulfide (CdS) is formed. - The reaction can be represented as: \[ \text{Cd}^{2+} + \text{S}^{2-} \rightarrow \text{CdS} \downarrow \] - **Conclusion:** Statement B is correct. 3. **Statement C: Sulfide ion reacts with sodium nitroprusside and gives purple coloration.** - When sodium nitroprusside (Na4[Fe(CN)5NOS]) is added to a solution containing sulfide ions, a purple complex is formed, indicating the presence of sulfide ions. - The reaction can be represented as: \[ \text{Na}_2\text{S} + \text{Na}_4[\text{Fe(CN)}_5\text{NOS}] \rightarrow \text{purple complex} \] - **Conclusion:** Statement C is correct. 4. **Statement D: Free H2S gas reacts to form precipitate with tetraoxide plumbates solution.** - Hydrogen sulfide (H2S) gas reacts with lead(IV) oxide (PbO2) or lead(II) salts to form lead sulfide (PbS), which is a black precipitate. - The reaction can be represented as: \[ \text{H}_2\text{S} + \text{Pb}^{2+} \rightarrow \text{PbS} \downarrow + 2\text{H}^+ \] - **Conclusion:** Statement D is correct. ### Final Conclusion: All statements A, B, C, and D are correct.

To determine which of the statements regarding soluble sulfides and their reactions are correct, we will analyze each statement step by step. ### Step-by-Step Solution: 1. **Statement A: Soluble sulfide gives black precipitate with silver nitrate solution which is soluble in hot dilute nitric acid.** - When soluble sulfides (like sodium sulfide, Na2S) react with silver nitrate (AgNO3), they form a black precipitate of silver sulfide (Ag2S). - The reaction can be represented as: \[ ...
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