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Which of the following statement(s) is(a...

Which of the following statement(s) is(are) incorrect ?

A

In thioure test for nitric ,a green coloured solution is obtained

B

it is not necessary to carry out the chromyl chloride test in a dry test tube

C

In `PbNO_(3)` the brown ring test can be performed with its water extract

D

Suspension of `CdCO_(4)` gives black ppt , with sodium sulphide solution

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statements are incorrect from the given options, we will analyze each statement one by one based on the knowledge of qualitative inorganic salt analysis. ### Step-by-Step Solution: 1. **Analyze Option A:** - **Statement:** "In thorium test for nitrite, a green colored solution is obtained." - **Analysis:** The thorium test for nitrite actually produces a deep red coloration due to the formation of Fe-S-C-N-Al(III). Therefore, the statement claiming a green color is incorrect. - **Conclusion:** Option A is incorrect. 2. **Analyze Option B:** - **Statement:** "It is not necessary to carry out the chromyl chloride test in a dry test tube." - **Analysis:** The chromyl chloride test must be performed in a dry test tube because the presence of moisture can lead to the formation of H2CrO4 and HCl, which would interfere with the test. Thus, the statement is incorrect. - **Conclusion:** Option B is incorrect. 3. **Analyze Option C:** - **Statement:** "In lead nitrate, a brown ring test can be performed with its water extract; a white precipitate of lead sulfate is formed, and hence the brown ring is not visible." - **Analysis:** The brown ring test involves the formation of a complex with iron and nitrate ions. If a white precipitate of lead sulfate forms, it can indeed hinder the visibility of the brown ring. Thus, this statement is also incorrect. - **Conclusion:** Option C is incorrect. 4. **Analyze Option D:** - **Statement:** "Suspension of cadmium CO3 gives a black precipitate with sodium sulfide solution." - **Analysis:** Cadmium carbonate (CdCO3) actually gives a yellow precipitate of cadmium sulfide (CdS) when reacted with sodium sulfide (Na2S), not a black precipitate. Therefore, this statement is incorrect. - **Conclusion:** Option D is incorrect. ### Final Conclusion: All options A, B, C, and D are incorrect.

To determine which statements are incorrect from the given options, we will analyze each statement one by one based on the knowledge of qualitative inorganic salt analysis. ### Step-by-Step Solution: 1. **Analyze Option A:** - **Statement:** "In thorium test for nitrite, a green colored solution is obtained." - **Analysis:** The thorium test for nitrite actually produces a deep red coloration due to the formation of Fe-S-C-N-Al(III). Therefore, the statement claiming a green color is incorrect. - **Conclusion:** Option A is incorrect. ...
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