Home
Class 12
CHEMISTRY
Assertion: When a solution of Na(2)ZnO(2...

Assertion: When a solution of `Na_(2)ZnO_(2)` is acidified with dilute HCl and treated with `H_(2)S,` a precipitate of ZnS is formed.
Reason: `Na_(2)ZnO_(2)` is decomposed by HCl to give `Zn^(2+)` ions.

A

If both (A) and (B) are correct and (R ) is the correct explqanation of (A)

B

If both (A) and (B) are correct but (R ) is not the correct explqanation of (A)

C

If (A) is correct ,but (R ) is incorrect

D

If (A) is incorrect ,but (R ) is correct

Text Solution

Verified by Experts

The correct Answer is:
d

Correct assertion (A)
`Na_(2)ZnO_(2) `+ `H_(2)S` rarr `overset(ZnS)underset((white))` + `2NaOH`
`NaZnO_(2)` is not acidified before passing `H_(2)S`
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE INORGANIC SALT ANALYSIS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Integer) (Naming And Terminology|15 Videos
  • QUALITATIVE INORGANIC SALT ANALYSIS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Fill In The Blanks)|42 Videos
  • QUALITATIVE INORGANIC SALT ANALYSIS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Single Correct) Part-D (Miscellaneous)|6 Videos
  • P-BLOCK GROUP 18 ELEMENTS - THE INERT GASES

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 5.1 (Objective)|14 Videos
  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise SUBJECTIVE TYPE|4 Videos

Similar Questions

Explore conceptually related problems

When a solution of Na_(2)Cr_(2)O_(7) is treated with amyl alcohol and acidified H_(2)O_(2) , the layer of ayl alcohol turns blue. What is the blue colouration?

Assertion: Na_(2)O_(2) is coloured and paramagnetic Reason: Na_(2)O_(2) is superoxide

Assertion : In the extraction of Ag, complex Na[Ag(CN)_(2)] is reacted with Zn. Reason : Zn is d-block transition metal.

An aqueous solution of a white salt A gives a white precipitate B on treatment with dilute HCl in cold condition. B is soluble in boiling water. An aqeous solution of A gives a yellow precipitate on treatment with a solution of K_(2)CrO_(4) . The soda extract of A is acidified with diolute H_(2)SO_(4) , boiled to remove CO_(2) and treated with a freshly prepared solution of FeSO_(4) . concentratd H_(2)SO_(4) is added to the resulting solution. a brownn ring is formed at the junction of the two layers. Q. The salt A is:

A solution of Cu^(2+) Zn^(2+) Bi^(3+) . Mn^(2+) and Co^(2+) at pH = 1 is reacted with H_(2)S . Which ions will be precipitated as sulphide?

In qualitative analysis when H_(2)S is passed through an aqueous solution of salt acidified with dil. HCl, a black precipitate is obtained. On boiling the precipitate with dil. HNO_(3) , it forms a solution of blue colour. Addition of excess of aqueous solution of ammonia to this solution gives

(i) A white solid mixture of two salts containing a common cations in insoluble in water. It dissolves in dilute HCl producing some gases (with effervescence) that turn an acidified dichromate solution gren. After the gases are passed through the acidified dichromate solution, the emerging gas turns baryta water milky. (ii) On treatment with dilute HNO_(3) , the white solid gives a solution which does not directly give a precipitate with a BaCl_(2) solution but gives a white precipitate when warmed with H_(2)O_(2) and then treated with a BaCl_(2) solution. (iii) The solution of the mixture in dilute HCl, when treated with NH_(4)Cl,NH_(4)OH and an Na_(2)HPO_(4) solution, gives a white precipitate. Q. The white precipitate obtained in (ii) indicates the presence of a:

(i) A white solid mixture of two salts containing a common cations in insoluble in water. It dissolves in dilute HCl producing some gases (with effervescence) that turn an acidified dichromate solution gren. After the gases are passed through the acidified dichromate solution, the emerging gas turns baryta water milky. (ii) On treatment with dilute HNO_(3) , the white solid gives a solution which does not directly give a precipitate with a BaCl_(2) solution but gives a white precipitate when warmed with H_(2)O_(2) and then treated with a BaCl_(2) solution. (iii) The solution of the mixture in dilute HCl, when treated with NH_(4)Cl,NH_(4)OH and an Na_(2)HPO_(4) solution, gives a white precipitate. Q. The white precipitate obtained in (iii) consists of:

Zn gives H_(2) gas with H_(2)SO_(4) and HCl but not with HNO_(3) because

An acidic solution contains both Zn^(2+) and Hg^(2+) ions. Which ion will get precipitated passing H_2S into it ?