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When KNO(2) and CH(2)COOH is added as Co...

When `KNO_(2)` and `CH_(2)COOH` is added as `CoCl_(2)` solution, yellow ppt of `K_(4)[Cu(NO_(2))_(6)]` is formed.

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To solve the question regarding the formation of a yellow precipitate when `KNO2` and `CH3COOH` are added to a `CoCl2` solution, we will follow a systematic approach. ### Step-by-Step Solution: 1. **Identify the Reactants:** - The reactants in this case are potassium nitrite (`KNO2`), acetic acid (`CH3COOH`), and cobalt(II) chloride (`CoCl2`). 2. **Understand the Reaction:** - When `KNO2` (which provides `NO2-` ions) is added to `CoCl2`, the cobalt(II) ions (`Co^2+`) can react with the nitrite ions. - The presence of acetic acid (`CH3COOH`) provides an acidic medium which can influence the reaction. 3. **Write the Expected Reaction:** - The expected reaction can be represented as: \[ Co^{2+} + 3 NO_2^{-} + 6 H^+ \rightarrow K_3[Co(NO_2)_6] + H_2O + NO \] - Here, `K3[Co(NO2)6]` is the complex formed, and it is a precipitate. 4. **Analyze the Precipitate:** - The statement claims that `K4[Cu(NO2)6]` is formed, which is incorrect. - The correct complex formed is `K3[Co(NO2)6]`, which is a yellow precipitate. 5. **Conclusion:** - The statement that a yellow precipitate of `K4[Cu(NO2)6]` is formed is false. Instead, the correct complex is `K3[Co(NO2)6]`. ### Final Answer: The statement is **False**. The yellow precipitate formed is `K3[Co(NO2)6]`, not `K4[Cu(NO2)6]`.

To solve the question regarding the formation of a yellow precipitate when `KNO2` and `CH3COOH` are added to a `CoCl2` solution, we will follow a systematic approach. ### Step-by-Step Solution: 1. **Identify the Reactants:** - The reactants in this case are potassium nitrite (`KNO2`), acetic acid (`CH3COOH`), and cobalt(II) chloride (`CoCl2`). 2. **Understand the Reaction:** ...
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (True And False )
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  2. K(sp) of Mg(OH)(2) is 1xx10^(-12), 0.01M MgCI(2) will be precipitating...

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  3. There is ppt. of solute AB if its product is greater than K(sp) val...

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  4. Chlorine gas is passed into a solution containing KF, KI and KBr and C...

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  5. When H(2)S gas is passed into aq ZnCl(2) solution white ppt of ZnS is...

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  6. Dilute H(2)SO(4) can be used in group of dil HCI. True/False

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  7. NH(4)CI can be replaced by (NH(4))(2)SO(4) in group III.

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  8. Alkaline solution of NH(4)Cl gives ppt with K(2)HgI(4)

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  9. When KNO(2) and CH(2)COOH is added as CoCl(2) solution, yellow ppt of ...

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  10. K(4)[Fe(CN)(6)] is used to test Cu^(2+),Fe^(2+),Zn^(2+),Cd^(2+)

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  11. Hg(2)Cl(2) is black ened by NH(3) due to formation of iodide of mi...

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  12. White ppt of PbCl(2) is soluble in aq NH(3). (T/F)

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  13. If acidified solution of K(2)Cr(2)O(7) turm green on addition of...

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  14. In group II, Formqation of whichsh tarbidity on dilation with H(2)O ...

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  15. NaOH can be used to seprate Al(OH)(3) and Zn(OH)(2) . (T/F)

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  16. NH(4)SCN can be used to make distanction between Cu^(2+) and Co^(2+)...

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  17. Yellow ammonium sulphide (YAS) can be used to seprate SnS and As(2)S...

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  18. NaOH can be used to seprate Al(OH)(3) and Zn(OH)(2) . (T/F)

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  19. AlCl(2) is soluble is axcess of NaOH forming sodium metaaluminate ...

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  20. BaBr(2) gives yellow ppt with AgNO(3) as well as with K(2)CrO(4). (T...

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