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KCI + "conc" H(2)SO(4) + K(2)Cr(2)O(7) o...

`KCI + "conc" H_(2)SO_(4) + K_(2)Cr_(2)O_(7) overset(Delta) to (X) overset(NaOH) to (Y),(X) ` is reddish brown coloured gas soluble in `NaOH` forming `(Y),(X) and (Y) `are

A

`Cr_(2)OCI_(2)Na_(2)CrO_(3)`

B

`Cr_(2)O_(2)CI_(2)Na_(2)CrO_(3)`

C

`CrO_(2)CI_(2)Na_(2)CrO_(6)`

D

`CrO_(2)CI_(2)Na_(2)CrO_(4)`

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The correct Answer is:
To solve the problem step by step, we will analyze the reaction and identify the compounds involved. ### Step 1: Identify the Reactants The reactants given in the question are: - Potassium Chloride (KCl) - Concentrated Sulfuric Acid (H₂SO₄) - Potassium Dichromate (K₂Cr₂O₇) ### Step 2: Understand the Reaction When KCl, concentrated H₂SO₄, and K₂Cr₂O₇ are heated together, they undergo a reaction that produces a reddish-brown gas. This gas is known as chromyl chloride (CrO₂Cl₂). ### Step 3: Identify Product X The reddish-brown gas produced from the reaction is: - **X = Chromyl Chloride (CrO₂Cl₂)** ### Step 4: Reaction of X with NaOH Next, we need to determine what happens when the chromyl chloride (X) reacts with sodium hydroxide (NaOH). The reaction of chromyl chloride with NaOH produces sodium chromate (Na₂CrO₄) and sodium chloride (NaCl), along with water (H₂O). ### Step 5: Identify Product Y From the reaction of X with NaOH, we find that: - **Y = Sodium Chromate (Na₂CrO₄)** ### Step 6: Final Answer Thus, the final answer is: - **X = CrO₂Cl₂ (Chromyl Chloride)** - **Y = Na₂CrO₄ (Sodium Chromate)** ### Summary The products of the reaction are: - **X = CrO₂Cl₂** - **Y = Na₂CrO₄**
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