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SO(2) and CO(2) both turn lime water (A)...

`SO_(2)` and `CO_(2)` both turn lime water (A) milky coloured ,`SO_(2)` also turns `K_(2)Cr_(2)O_(7)//H^(o+)(B)` green while `O_(2)` is soluble in pyrogallol (C ) turning it black .These gases are to be detected in order by using these reagents .The order is

A

(A),(B) ,(C )

B

(B),(C) ,(A)

C

(B),(A) ,(C )

D

(A),(C) ,(B)

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The correct Answer is:
To determine the order in which the gases \( SO_2 \), \( CO_2 \), and \( O_2 \) can be detected using the reagents lime water (A), \( K_2Cr_2O_7/H^+ \) (B), and pyrogallol (C), we can analyze the reactions of each gas with the respective reagents. ### Step-by-Step Solution: 1. **Identify the Reactions:** - **Lime Water (A):** Both \( SO_2 \) and \( CO_2 \) turn lime water milky due to the formation of calcium carbonate. - **\( K_2Cr_2O_7/H^+ \) (B):** \( SO_2 \) reduces \( K_2Cr_2O_7 \) in acidic medium, turning it from orange to green. - **Pyrogallol (C):** \( O_2 \) reacts with pyrogallol, resulting in a color change to black due to the formation of a complex. 2. **Determine the Order of Detection:** - First, we should detect \( SO_2 \) using reagent B. Since \( SO_2 \) can reduce \( K_2Cr_2O_7 \), it will be absorbed first, and thus removed from the mixture. - Next, we can detect \( CO_2 \) using lime water (A). After \( SO_2 \) has been removed, \( CO_2 \) will react with lime water, turning it milky. - Finally, we can detect \( O_2 \) using pyrogallol (C). After both \( SO_2 \) and \( CO_2 \) have been removed, \( O_2 \) will react with pyrogallol, turning it black. 3. **Final Order of Detection:** - The order of detection is: **B (for \( SO_2 \)), A (for \( CO_2 \)), C (for \( O_2 \))**. ### Conclusion: The correct order for detecting the gases is **B, A, C**.
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