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NH(4)SCN can be used to test ion or mo...

`NH_(4)SCN` can be used to test ion or more out of `Fe^(3+) ,Co^(2+),Cu^(2+)`

A

`Fe^(3+) `only

B

`Co^(2+),Cu^(2+)`

C

`Fe^(2+),Cu^(2+)`

D

all

Text Solution

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The correct Answer is:
To determine which ions can be tested using ammonium thiocyanate (NH₄SCN), we will analyze the reactions of NH₄SCN with each of the given ions: Fe³⁺, Co²⁺, and Cu²⁺. ### Step-by-Step Solution: 1. **Testing for Fe³⁺ (Iron III ion)**: - When ammonium thiocyanate reacts with iron (III) chloride (FeCl₃), it forms a blood-red complex known as iron(III) thiocyanate (Fe(SCN)₃). - The reaction can be represented as: \[ FeCl_3 + 3 NH_4SCN \rightarrow Fe(SCN)_3 + 3 NH_4Cl \] - The formation of a blood-red color indicates the presence of Fe³⁺ ions. 2. **Testing for Co²⁺ (Cobalt II ion)**: - When ammonium thiocyanate reacts with cobalt (II) chloride (CoCl₂), it forms a blue complex known as cobalt(II) thiocyanate (Co(SCN)₄²⁻). - The reaction can be represented as: \[ CoCl_2 + 4 NH_4SCN \rightarrow Co(SCN)_4 + 2 NH_4Cl \] - The formation of a blue color indicates the presence of Co²⁺ ions. 3. **Testing for Cu²⁺ (Copper II ion)**: - When ammonium thiocyanate reacts with copper (II) chloride (CuCl₂), it forms a black precipitate known as copper(I) thiocyanate (CuSCN). - The reaction can be represented as: \[ CuCl_2 + 2 NH_4SCN \rightarrow CuSCN + 2 NH_4Cl \] - The formation of a black precipitate indicates the presence of Cu²⁺ ions. ### Conclusion: Ammonium thiocyanate can be used to test for all three ions: Fe³⁺, Co²⁺, and Cu²⁺. Therefore, the answer is that NH₄SCN can be used to test for all of these ions. ### Final Answer: All of these ions (Fe³⁺, Co²⁺, Cu²⁺) can be tested using NH₄SCN. ---
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Ex 8.2
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  4. K(4)[Fe(CN)(6)] can be used to detect one or more out of Fe^(2+)...

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  6. Ag(2)S is soluble in NaCN due to formation of

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  10. Solution of a salt in dil H(2)SO(4) produces deep blue colour with st...

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  12. A mixture when heated with dil H(2)SO(4) does not evolve brown vapour...

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  13. To solution of a salt in acid medium AgNO(3) is added a white ppts r...

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  18. When a salt is heated with dil H(2)SO(4) and KMnO(4) solution the pi...

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  19. Ring test for mirates conformed by acidifying prepared FeSO(4) soi...

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