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Why do we not prefer to prepare original...

Why do we not prefer to prepare original solution of cations in conc. `H_(2)SO_(4)` or conc. `HNO_(3)`?

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### Step-by-Step Solution: 1. **Understanding the Context**: The question asks why concentrated sulfuric acid (H₂SO₄) and concentrated nitric acid (HNO₃) are not preferred for preparing original solutions of cations for qualitative analysis. 2. **Role of Concentrated Acids**: Both concentrated H₂SO₄ and HNO₃ are strong acids and also act as oxidizing agents. This means they can react with other substances, potentially altering them. 3. **Oxidizing Nature of Acids**: - Concentrated H₂SO₄ can oxidize certain compounds. For example, when H₂S (hydrogen sulfide), which is commonly used for detecting group 2 metals, is introduced, it can be oxidized by H₂SO₄. ...
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Viva Voce Questions And Part-C (Analysis Of Cations)
  1. Why is it necessary to prepare original solution for the detection of ...

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  2. Why do we not prefer to prepare original solution of cations in conc....

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  3. What is solubility product? Explain its importance in qualitative anal...

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  4. What is the basis of classification of cations into different group ?

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  5. Why are only Pb^(2+),Ag^(o+) and Hg(2)^(2+) ions precipitated in group...

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  6. Why is lead placed in group I as well in II?

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  7. Is it necessary to acidify a solution before group II cations are prec...

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  8. Give the reason for the formation of a light yellow or white ppt. in t...

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  9. Why do we Prefer HCl for preparing solution of cations?

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  10. Is it advisable to use conc. HCI in place of dilute HCI for preparing ...

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  11. Why is it essential to boil off H(2)S gas before proceeding to group I...

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  12. Can the solution be acidified with HNO(3) in group II before passing H...

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  13. What can it be, if the precipitate of group I is soluble in hot water ...

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  14. Why do we not prefer to prepare original solution of cations in conc....

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  15. Group I filtrate is made moderately acidic before proceeding to group ...

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  16. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  17. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  18. Why is it essential to oxidise ferrous salt to ferric salt in group II...

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  19. Can NH(4)Cl be replaced by any other ammonium salt for the precipitati...

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  20. How will you distinguish between ferrous and ferric salts?

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