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Why are only Pb^(2+),Ag^(o+) and Hg(2)^(...

Why are only `Pb^(2+),Ag^(o+)` and `Hg_(2)^(2+)` ions precipitated in group I?

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To understand why only \( \text{Pb}^{2+}, \text{Ag}^{+}, \) and \( \text{Hg}_2^{2+} \) ions are precipitated in Group I during qualitative inorganic salt analysis, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Group I Cations**: Group I cations in qualitative analysis are specifically \( \text{Pb}^{2+} \) (lead), \( \text{Ag}^{+} \) (silver), and \( \text{Hg}_2^{2+} \) (mercury). These ions are known for forming insoluble chlorides when treated with hydrochloric acid (HCl). 2. **Reagent Used**: ...
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Viva Voce Questions And Part-C (Analysis Of Cations)
  1. What is solubility product? Explain its importance in qualitative anal...

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  2. What is the basis of classification of cations into different group ?

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  3. Why are only Pb^(2+),Ag^(o+) and Hg(2)^(2+) ions precipitated in group...

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  4. Why is lead placed in group I as well in II?

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  5. Is it necessary to acidify a solution before group II cations are prec...

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  6. Give the reason for the formation of a light yellow or white ppt. in t...

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  7. Why do we Prefer HCl for preparing solution of cations?

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  8. Is it advisable to use conc. HCI in place of dilute HCI for preparing ...

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  9. Why is it essential to boil off H(2)S gas before proceeding to group I...

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  10. Can the solution be acidified with HNO(3) in group II before passing H...

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  11. What can it be, if the precipitate of group I is soluble in hot water ...

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  12. Why do we not prefer to prepare original solution of cations in conc....

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  13. Group I filtrate is made moderately acidic before proceeding to group ...

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  14. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  15. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  16. Why is it essential to oxidise ferrous salt to ferric salt in group II...

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  17. Can NH(4)Cl be replaced by any other ammonium salt for the precipitati...

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  18. How will you distinguish between ferrous and ferric salts?

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  19. Can we add NH(4)OH first and NH(4)Cl later in the analysis of group II...

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  20. Can we use NaCla and NaOH in place of Na(4)Cl and NH(4)OH in the group...

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