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Give the reason for the formation of a light yellow or white ppt. in the group II even if it may not be because of some metal ion.

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To address the question regarding the formation of a light yellow or white precipitate in Group II, even if it may not be due to some metal ion, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Group II Cations**: - Group II cations include Pb²⁺ (Lead), Cd²⁺ (Cadmium), Cu²⁺ (Copper), and Hg²⁺ (Mercury). These ions typically form precipitates when treated with reagents like dilute HCl and hydrogen sulfide (H₂S). 2. **Formation of Metal Sulfides**: ...
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Viva Voce Questions And Part-C (Analysis Of Cations)
  1. Why is lead placed in group I as well in II?

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  2. Is it necessary to acidify a solution before group II cations are prec...

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  3. Give the reason for the formation of a light yellow or white ppt. in t...

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  4. Why do we Prefer HCl for preparing solution of cations?

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  5. Is it advisable to use conc. HCI in place of dilute HCI for preparing ...

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  6. Why is it essential to boil off H(2)S gas before proceeding to group I...

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  7. Can the solution be acidified with HNO(3) in group II before passing H...

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  8. What can it be, if the precipitate of group I is soluble in hot water ...

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  9. Why do we not prefer to prepare original solution of cations in conc....

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  10. Group I filtrate is made moderately acidic before proceeding to group ...

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  11. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  12. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  13. Why is it essential to oxidise ferrous salt to ferric salt in group II...

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  14. Can NH(4)Cl be replaced by any other ammonium salt for the precipitati...

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  15. How will you distinguish between ferrous and ferric salts?

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  16. Can we add NH(4)OH first and NH(4)Cl later in the analysis of group II...

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  17. Can we use NaCla and NaOH in place of Na(4)Cl and NH(4)OH in the group...

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  18. Why are Zn,MnNi,Co not precipitated n the group III as hydroxides?

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  19. Why are the group IV cations not precipitated as sulphides on passing ...

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  20. Why is a brownish ppt. obtained in group II even if iron aluminium and...

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