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Why do we Prefer HCl for preparing solut...

Why do we Prefer HCl for preparing solution of cations?

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### Step-by-Step Solution: 1. **Understanding the Role of HCl**: Hydrochloric acid (HCl) is a strong mineral acid commonly used in qualitative inorganic analysis. It is important to note that HCl is used to prepare solutions of cations. 2. **Solubility of Cations**: Most cations are soluble in dilute HCl. This includes common cations such as Mn²⁺, Ca²⁺, and Zn²⁺. The solubility of these cations in HCl allows for their detection and analysis in qualitative tests. 3. **Exceptions to Solubility**: There are exceptions to this solubility rule. Specifically, the cations Ag⁺ (silver), Pb²⁺ (lead), and Hg₂²⁺ (mercurous) are not soluble in dilute HCl. Instead, they form precipitates when HCl is added to their solutions. ...
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Viva Voce Questions And Part-C (Analysis Of Cations)
  1. Is it necessary to acidify a solution before group II cations are prec...

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  2. Give the reason for the formation of a light yellow or white ppt. in t...

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  3. Why do we Prefer HCl for preparing solution of cations?

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  4. Is it advisable to use conc. HCI in place of dilute HCI for preparing ...

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  5. Why is it essential to boil off H(2)S gas before proceeding to group I...

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  6. Can the solution be acidified with HNO(3) in group II before passing H...

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  7. What can it be, if the precipitate of group I is soluble in hot water ...

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  8. Why do we not prefer to prepare original solution of cations in conc....

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  9. Group I filtrate is made moderately acidic before proceeding to group ...

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  10. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  11. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  12. Why is it essential to oxidise ferrous salt to ferric salt in group II...

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  13. Can NH(4)Cl be replaced by any other ammonium salt for the precipitati...

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  14. How will you distinguish between ferrous and ferric salts?

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  15. Can we add NH(4)OH first and NH(4)Cl later in the analysis of group II...

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  16. Can we use NaCla and NaOH in place of Na(4)Cl and NH(4)OH in the group...

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  17. Why are Zn,MnNi,Co not precipitated n the group III as hydroxides?

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  18. Why are the group IV cations not precipitated as sulphides on passing ...

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  19. Why is a brownish ppt. obtained in group II even if iron aluminium and...

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  20. Why sometimes, a black coloured precipitate obtained in group IV even ...

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