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Is it advisable to use conc. HCI in plac...

Is it advisable to use conc. HCI in place of dilute HCI for preparing original solution

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**Step-by-Step Solution:** 1. **Understanding the Question**: The question asks whether it is advisable to use concentrated hydrochloric acid (HCl) instead of dilute HCl for preparing an original solution in the context of qualitative inorganic salt analysis. 2. **Role of HCl in Precipitation Reactions**: Hydrochloric acid is often used in qualitative analysis to precipitate certain ions. In this case, we are particularly interested in lead ions (Pb²⁺) and their precipitation as lead(II) chloride (PbCl₂). 3. **Using Concentrated HCl**: While concentrated HCl can be used to prepare the solution, it is important to note that using concentrated HCl may lead to the formation of complexes. For example, lead ions may form soluble complexes with chloride ions when concentrated HCl is used. ...
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Viva Voce Questions And Part-C (Analysis Of Cations)
  1. Give the reason for the formation of a light yellow or white ppt. in t...

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  2. Why do we Prefer HCl for preparing solution of cations?

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  3. Is it advisable to use conc. HCI in place of dilute HCI for preparing ...

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  4. Why is it essential to boil off H(2)S gas before proceeding to group I...

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  5. Can the solution be acidified with HNO(3) in group II before passing H...

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  6. What can it be, if the precipitate of group I is soluble in hot water ...

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  7. Why do we not prefer to prepare original solution of cations in conc....

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  8. Group I filtrate is made moderately acidic before proceeding to group ...

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  9. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  10. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  11. Why is it essential to oxidise ferrous salt to ferric salt in group II...

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  12. Can NH(4)Cl be replaced by any other ammonium salt for the precipitati...

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  13. How will you distinguish between ferrous and ferric salts?

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  14. Can we add NH(4)OH first and NH(4)Cl later in the analysis of group II...

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  15. Can we use NaCla and NaOH in place of Na(4)Cl and NH(4)OH in the group...

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  16. Why are Zn,MnNi,Co not precipitated n the group III as hydroxides?

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  17. Why are the group IV cations not precipitated as sulphides on passing ...

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  18. Why is a brownish ppt. obtained in group II even if iron aluminium and...

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  19. Why sometimes, a black coloured precipitate obtained in group IV even ...

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  20. Why excess of NH(4)OH is used in precipitating the sulphides of group ...

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