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Can the solution be acidified with HNO(3...

Can the solution be acidified with `HNO_(3)` in group II before passing `H_(2)S` gas?

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To determine whether the solution can be acidified with nitric acid (HNO₃) in Group II before passing hydrogen sulfide (H₂S) gas, we need to consider the chemical properties of HNO₃ and its effect on H₂S. ### Step-by-Step Solution: 1. **Understanding Group II Analysis**: In qualitative inorganic analysis, Group II cations include metals like lead (Pb²⁺), mercury (Hg²⁺), and cadmium (Cd²⁺). These cations are typically precipitated as sulfides when H₂S is passed through the solution. 2. **Role of Nitric Acid (HNO₃)**: ...
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Find out the number of cation (s) which form(s) black ppt. (soluble in hot and dilute HNO_(3) ) on passing H_(2)S gas into their salt solution? Mg^(2+)(aq.)Cu^(2+)(aq.),Ba^(2+)(aq.),Fe^(3+)(aq.),Ag^(+)(aq.),Al^(3+)(aq.),Hg^(2+)(aq.),Pb^(2+)(aq.),Mn^(2+)(aq.)

Assertion :When H_(2)S is passed through a solution of CuSO_(4) no precipitate of CuS is abtain until the solution is acidified with HCI Reasion: The solution products constant of CuS is not so high as to require a high concen tration of S^(2-) for the precipitate of CuS

Is it necessary to acidify a solution before group II cations are precipitated with H_(2)S ?

Why are the group IV cations not precipitated as sulphides on passing H_(2)S gas through group II solution?

Sodium carbonate extract is acidified with HNO_(3) only in the identification of halides. Comment.

In qualitative analysis when H_(2)S is passed through an aqueous solution of salt acidified with dil. HCL, a block precipitate is obtainned .On boiling the precipitate with dil. HNO_(3) it forms a solution of blue colour . Addition of excess of aqueous solution of ammonia to this solution given ....... .

Even in the absence of group II,colloidal yellowish ppt appears on passing H_(2)S gas , it may be due to the presence of (a) _____.

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Assertion: A solution of AgCl in NH_(4)OH gives a white precipitate when acidified with HNO_(3) . Reason: [Ag(NH_(3))_(2)]^(+) decomposes in the presence of HNO_(3) .

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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Viva Voce Questions And Part-C (Analysis Of Cations)
  1. Is it advisable to use conc. HCI in place of dilute HCI for preparing ...

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  2. Why is it essential to boil off H(2)S gas before proceeding to group I...

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  3. Can the solution be acidified with HNO(3) in group II before passing H...

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  4. What can it be, if the precipitate of group I is soluble in hot water ...

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  5. Why do we not prefer to prepare original solution of cations in conc....

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  6. Group I filtrate is made moderately acidic before proceeding to group ...

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  7. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  8. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  9. Why is it essential to oxidise ferrous salt to ferric salt in group II...

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  10. Can NH(4)Cl be replaced by any other ammonium salt for the precipitati...

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  11. How will you distinguish between ferrous and ferric salts?

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  12. Can we add NH(4)OH first and NH(4)Cl later in the analysis of group II...

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  13. Can we use NaCla and NaOH in place of Na(4)Cl and NH(4)OH in the group...

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  14. Why are Zn,MnNi,Co not precipitated n the group III as hydroxides?

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  15. Why are the group IV cations not precipitated as sulphides on passing ...

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  16. Why is a brownish ppt. obtained in group II even if iron aluminium and...

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  17. Why sometimes, a black coloured precipitate obtained in group IV even ...

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  18. Why excess of NH(4)OH is used in precipitating the sulphides of group ...

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  19. Why sometimes colloidal precipitate is obtained in group IV? Comment

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  20. Why is NH(4)Cl essential in the precipitation of group V cations?

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