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Can we use NaCla and NaOH in place of Na...

Can we use NaCla and NaOH in place of `Na_(4)Cl` and `NH_(4)OH` in the group III cation precipitation.

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To determine whether we can use NaCl and NaOH in place of NH4Cl and NH4OH in the group III cation precipitation, we need to analyze the roles of these compounds in the precipitation process. ### Step-by-Step Solution: 1. **Understanding the Role of NH4Cl**: - NH4Cl (Ammonium Chloride) is used in the precipitation of group III cations because it provides NH4+ ions, which suppress the dissociation of hydroxide ions (OH-) due to the common ion effect. This leads to a decrease in the concentration of hydroxide ions in the solution. **Hint**: Remember that NH4Cl contributes NH4+ ions, which help control the concentration of hydroxide ions. ...
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Why do we add excess of NH_(4)Cl and NH_(4)OH in the precipitation of group III cations?

Why do we add excess of NH_(4)Cl and NH_(4)OH in the precipitation of group III cations?

Can we add NH_(4)OH first and NH_(4)Cl later in the analysis of group III cations?

NH_(4)CI can be replaced by (NH_(4))_(2)SO_(4) in group III.

Can NaOH be used in place of NH_4OH to precipitate the cations of group III in qualitative analysis?

Heating an ammoniacal solution of MgSO_(4) in the presence of NH_(4)Cl and Na_(2)HPO_(4) causes the precipitation of:

Hg_2Cl_2 + NH_4OH to

An inorganic Lewis acid (X) shows the following reactions : (a) It fumes in moist air. (b) The intensity of fumes increase when a rod dippod in NH_(4) OH is brought near it. ( c) To an aqueous solution of (X) , addition of NH_(4)Cl and NH_(4)OH gives a precipitate which dissolves in NaOH solution. (d) An acidic solution of (X) does not give a precipitate with H_(2) S . Identify (X) and gives chemical reactions for (a) to (d) .

An inorganic Lewis acid (X) shows the following reactions : (a) It fumes in moist air. (b) The intensity of fumes increase when a rod dippod in NH_(4) OH is brought near it. ( c) To an aqueous solution of (X) , addition of NH_(4)Cl and NH_(4)OH gives a precipitate which dissolves in NaOH solution. (d) An acidic solution of (X) does not give a precipitate with H_(2) S . Identify (X) and gives chemical reactions for (a) to (d) .

A solution when diluted with H_(2)O And boiled gives a white precipitate .On the addition of excess NH_(4)Cl & NH_(4)OH the volume of the precipitate decreases leaving behind a white gelationtious precipitate identify the precipitate which dissolves in NH_(4)OH//NH_(4)Cl :

CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Viva Voce Questions And Part-C (Analysis Of Cations)
  1. How will you distinguish between ferrous and ferric salts?

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  2. Can we add NH(4)OH first and NH(4)Cl later in the analysis of group II...

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  3. Can we use NaCla and NaOH in place of Na(4)Cl and NH(4)OH in the group...

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  4. Why are Zn,MnNi,Co not precipitated n the group III as hydroxides?

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  5. Why are the group IV cations not precipitated as sulphides on passing ...

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  6. Why is a brownish ppt. obtained in group II even if iron aluminium and...

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  7. Why sometimes, a black coloured precipitate obtained in group IV even ...

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  8. Why excess of NH(4)OH is used in precipitating the sulphides of group ...

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  9. Why sometimes colloidal precipitate is obtained in group IV? Comment

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  10. Why is NH(4)Cl essential in the precipitation of group V cations?

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  11. Does the excess of NH(4)Cl affect the precipitation of group V cations...

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  12. Why are all aqueous solution of the cobaltous salts pink?

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  13. At times NH(4)OH is added before adding (NH(4))(2)CO(3) to precipitate...

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  14. Na(2)CO(3) cannot be used in place of (NH(4))(2)CO(3) for the precipit...

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  15. Why is CaSO(4) not precipitated on adding ammonium sulphate to a solut...

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  16. At times warming is suggested while precipitating group V cation. Expl...

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  17. Na(2)CO(3) cannot be used in place of (NH(4))(2)CO(3) for the precipit...

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  18. Why do we test group V cations in the order of Ba, Sr, and Ca?

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  19. Why is only acetic acid employed for dissolving the group V ppt.?

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  20. Sometimes no precipitate is obtained even if group V radicals are pres...

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