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What is the role of graphite rod in the electrometallurgy of aluminium?

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In the electrometallurgy of aluminium a fused mixture of alumina, cryolite and flourspar `(CaF_2)` is electrolysed using graphite as anode and graphite lined iron as cathode. During electrolysis , Al is liberated at the cathode while CO and `CO_2` are liberated at the anode.
At cathode: `Al_(mel t)toAl(1)`
AT anode: `C_(s)+O^(2-)toCO_(g)+2r^(ɵ)`
`C_(s)+2O^(2-)toCO_2+4e^(ɵ)`
If instead of graphite, some metal is used as the anode then `O_2` liberated will not only oxidese the metal of the electrode but would also convert some of the Al liberated at the cathod back to `Al_2O_3`. Since graphite is much cheaper than any metal, therefore graphite is used as the anode, thus the role of graphite in electrometallurgy of Al is to prevent the liberation of `O_2` at the anode which may otherwise oxidese some of the liberated Al back to `Al_2O_3`.
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CENGAGE CHEMISTRY ENGLISH-APPENDIX INORGANIC VOLUME 2-Exercises
  1. The choice of a reducing agent in a particular case depends on thermod...

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  2. Name the processes from which chlorine is obtained as a by-product. Wh...

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  3. What is the role of graphite rod in the electrometallurgy of aluminium...

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  4. Outline the principles of refining of metals by the following methods:...

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  5. Predict conditions under which Al might be expected to reduce MgO. (...

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  6. Discuss the general characteristics of Group 15 elements with referenc...

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  7. Why does the reactivity of nitrogen differ from phosphorus?

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  8. Discuss the trends in chemical reactivity of group 15 elements.

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  9. Why does NH(3) form hydrogen bond but PH(3) does not?

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  10. How is nitrogen prepared in the laboratory? Write the chemical equatio...

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  11. State three different chemical compounds other than acids manufactured...

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  12. Pb + conc. HNO(3) gives

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  13. Give the resonating structures of NO(2) and N(2)O(5).

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  14. The HNH angle value is higher than HPH, HAsH and HSbH angles. Why? ...

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  15. Why does R(3)P = O exist but R(3)N = O does not (R = alkyl group)?

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  16. Explain why NH(3) is basic while BiH3 is only feebly basic.

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  17. Nitrogen exists as diatomic molecule and phosphorus as P(4). Why?

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  18. Write main differences between the properties of white phosphorus and ...

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  19. Why does nitrogen show catenation properties less than phosphorus ?

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  20. Give the disproportionation reaction of H(3)PO(3).

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