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Explain why NH(3) is basic while BiH3 is...

Explain why `NH_(3)` is basic while BiH3 is only feebly basic.

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Both N in `NH_3` and `Bi` in `BiH_3` have a lone pair of electrons. Since the atomic size of N is less than Bi and N is more electronegative than Bi Hence electron density is more on N in `NH_3` than on Bi in `BiH_3`. Consequently the tendency to donate its lone pair is more in `NH_3` hence `NH_3` is more basic than `BiH_3`.
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CENGAGE CHEMISTRY ENGLISH-APPENDIX INORGANIC VOLUME 2-Exercises
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  2. Why does R(3)P = O exist but R(3)N = O does not (R = alkyl group)?

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  3. Explain why NH(3) is basic while BiH3 is only feebly basic.

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  4. Nitrogen exists as diatomic molecule and phosphorus as P(4). Why?

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  5. Write main differences between the properties of white phosphorus and ...

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  6. Why does nitrogen show catenation properties less than phosphorus ?

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  7. Give the disproportionation reaction of H(3)PO(3).

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  8. Can PCl(5) act as an oxidising as well as a reducing agent? Justify.

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  9. Justify the placement of O, S, Se, Te and Po in the same group of the ...

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  10. Why is dioxygen a gas but sulphur a solid?

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  11. Knowing the electron gain enthalpy values for O to O^(-) and O to O^(...

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  12. Which aerosols deplete ozone?

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  13. Describe the manufacture of H(2)SO(4) by contact process?

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  14. How is SO(2) an air pollutant?

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  15. Why are halogens strong oxidising agents?

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  16. Explain why fluorine forms only one oxoacid, HOF.

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  17. Although chlorine and oxygen have nearly same electronegativity yet on...

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  18. Write two uses of ClO(2).

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  19. Why are halogens coloured?

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  20. Write the reactions of F(2) and Cl(2) with water.

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