Home
Class 12
CHEMISTRY
Justify the placement of O, S, Se, Te an...

Justify the placement of O, S, Se, Te and Po in the same group of the periodic table in terms of electronic configuration, oxidation state and hydride formation.

Text Solution

Verified by Experts

(i). Electronic configuration: O, S, Se and Te have the same `ns^2np^4` valence shell electron configuration and hence are justified to be placed in group 16 of the periodic table.
`O(8)[He]2s^22p^4`
`S(16)[Ne]3s^23p^4`
`Se(34)[Ar]3d^(10)4s^24p^4`
`Te(52)[Kr]4d^(10)5s^25p^4`
(ii). Oxidation states: O, S, Se and Te need twio more electrons to form dinegative ion and acquire oxidation state of these elements shoud be -2. Oxygen predominantly and sulphur to some extent shows `O.S.-2`. Other elements of group 16, being less electronegative, have less stable `O.S.-2`. Since group 16 elements have 6 electrons in their valence shell, at maximum they can show `+6` O.S. other positive oxidation sattes shown by these elements is `+4` and `+6`. Thus on the basis of oxidation states shown by these elements they are justified to be placed in the same group i.e., group 16 of the periodic table.
(iii). Formation of hydrides: All the elements i.e., O,S Se and Te complete their respective octets by sharing of their valence electrons with 2 s-orbital of hydrogen to form hydrides of the type `EH_2` i.e., `H_2O,H_2S,H_2Se` and `H_2Te`. Thus on the basis of formation of hydrides of the general formula `EH_2` these elements are justified to be placed in the group ie., group 16 of the periodic table.
Promotional Banner

Topper's Solved these Questions

  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|26 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective Type|4 Videos

Similar Questions

Explore conceptually related problems

Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.

An element belongs to group 17 and period 3 of the periodic table. Write the following: Its electronic configuration.

With reference to period 3 of the periodic table - State: The electronic configuration of the element whose hydroxide is a weak base.

Predict the name and position of the element in the periodic table with the electronic configuration (n - 1) d^(8) n s^(2) for n = 5 .

if value of spin quantum number (s)=-1//2,0,+1//2 then calculate number of groups in the new form of periodic table if all other rules of electronic configurations are remain same.

if value of spin quantum number (s)=-1//2,0,+1//2 then calculate number of groups in the new form of periodic table if all other rules of electronic configurations are remain same.

In the long form of the periodic table the valence shell electronic configuration of 5s^(2)5p^(4) corresponds to the element present in:

To which block of the periodic table group 13 belongs.What is the general outer electronic configuration of this group?

Write the group and period numbers of oxygen from its electronic configuration (O = 8 = 2, 6).

Name or state with reference to the elements of the modern periodic table. The noble gas having an electronic configuration 2, 8, 8.

CENGAGE CHEMISTRY ENGLISH-APPENDIX INORGANIC VOLUME 2-Exercises
  1. Give the disproportionation reaction of H(3)PO(3).

    Text Solution

    |

  2. Can PCl(5) act as an oxidising as well as a reducing agent? Justify.

    Text Solution

    |

  3. Justify the placement of O, S, Se, Te and Po in the same group of the ...

    Text Solution

    |

  4. Why is dioxygen a gas but sulphur a solid?

    Text Solution

    |

  5. Knowing the electron gain enthalpy values for O to O^(-) and O to O^(...

    Text Solution

    |

  6. Which aerosols deplete ozone?

    Text Solution

    |

  7. Describe the manufacture of H(2)SO(4) by contact process?

    Text Solution

    |

  8. How is SO(2) an air pollutant?

    Text Solution

    |

  9. Why are halogens strong oxidising agents?

    Text Solution

    |

  10. Explain why fluorine forms only one oxoacid, HOF.

    Text Solution

    |

  11. Although chlorine and oxygen have nearly same electronegativity yet on...

    Text Solution

    |

  12. Write two uses of ClO(2).

    Text Solution

    |

  13. Why are halogens coloured?

    Text Solution

    |

  14. Write the reactions of F(2) and Cl(2) with water.

    Text Solution

    |

  15. How can you prepare Cl(2) from HCl and HCl from Cl(2)? Write reactions...

    Text Solution

    |

  16. What inspired N. Bartlett for carrying out reaction between Xe and PtF...

    Text Solution

    |

  17. What are the oxidation states of phosphorus in the following:

    Text Solution

    |

  18. Write balanced equations for the following: (i) NaCl is heated wit...

    Text Solution

    |

  19. How are xenon fluorides XeF(2), XeF(4) and XeF(6) obtained?

    Text Solution

    |

  20. With what neutral molecule is ClO^(–) isoelectronic? Is that molecule ...

    Text Solution

    |