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The chemistry of the actinoid elements i...

The chemistry of the actinoid elements is not so smooth as that of theb lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.

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Lanthanoids shw limited number of oxidation state e.g., `+2+3` and `+4` (out of which `+3` is most common). This is because of large energy gap between `4f,5d` and `6s` subshells. The dominant state of actinoids is also `+3` but they show a number of other oxidation states also,
e.g., uranium `(Z=92)` and plutonium `(Z=94)`, Show `+3`,`+4,+5` and `+6`, neptunium `(Z=94)` shows `+3,+4,+5` and `+7`, etc. This is due to small energy difference between 5f, 6d and 7s subshells of the actinoids.
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CENGAGE CHEMISTRY ENGLISH-APPENDIX INORGANIC VOLUME 2-Exercises
  1. What are alloys? Name an important alloy which contains some of the la...

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  2. What are inner transition elements? Decide which of the following atom...

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  3. The chemistry of the actinoid elements is not so smooth as that of the...

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  4. Which is the last element in the series of the actinoids? Write the el...

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  5. Use Hund’s rule to derive the electronic configuration of Ce^(3+) ion,...

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  6. Name the members of the lanthanoid series which exhibit +4 oxidation s...

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  7. Compare the chemistry of actinoids with that of the lanthanoids with s...

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  8. Write the electronic configurations of the elements with the atomic nu...

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  9. Compare the general characteristics of the first series of the transit...

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  10. Write down the number of 3d electrons in each of the following ions: ...

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  11. Comment on the statement that elements of the first transition series ...

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  15. Explain with two examples each of the following: coordination entity, ...

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  16. What is meant by unidentate, didentate and ambidentate ligands? Give t...

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  17. Specify the oxidation numbers of the metals in the following coordinat...

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  18. Using IUPAC norms write the formulas for the following (i) Tetrahydr...

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  19. Using IUPAC norms write the systematic names of the following: (i). ...

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  20. List various types of isomerism possible for coordinatior compounds, g...

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