Home
Class 12
CHEMISTRY
Use Hund’s rule to derive the electronic...

Use Hund’s rule to derive the electronic configuration of `Ce^(3+)` ion, and calculate its magnetic moment on the basis of ‘spin-only’ formula.

Text Solution

Verified by Experts

`Ce(Z=58)=4f^(1)5d^(1)6s^(2),Ce^(3+)=4f^(1)`
There is only one unpaired electgron, i.e., `n=1`, Hence,
`mu=sqrt(n(n+2))=sqrt((1(1+2))=sqrt(3)=1.73BM`
Promotional Banner

Topper's Solved these Questions

  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|26 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective Type|4 Videos

Similar Questions

Explore conceptually related problems

Use Hund's rule to derive the electronic configuration of Ce^(3+) ion, and calculatel its magntic moment on the basis of spin-only formula.

Magnetic moment of Ce^(3+) ion on the basis of 'spin-only' formula will be ______ B.M.

The calculated spin only magnetic moment of Cr^2+ ion is:

Transition metals and many of their compounds show paramagnetic behaviour where there are unpaired electron or electrons. The magnetic moment arises from the spin and orbital motions in ions or molecule. Magnetic moment of n unpaired electrons is given as mu=sqrt(n(n+2)) Bohr magneton Magnetic moment increases as the number of unpaired electrons increases. Q. There are three unpaired electrons in [Co(H_2O)_6]^(2+) and calculated value of magnetic moment on the basis of sqrt(n(n+2)) formula is 3.87 BM. which is lower than the expermental value of 4.40 BM. The reason for this difference is due to

Find electronic configuration and magnetic moment of Gd^(3+)

The correct electronic configuration and spin -only magnetic moment (BM) of Gd^(3+) (Z = 64) , respectively , are :

Calculate the spin only magentic moment of M^(2+) ion (Z=27) .

Write down the IUPAC name for each of the following complexes and indicate the oxidation state, electronic configuration and coordination number. Also give stereochemistry and magnetic moment of the complex CrCl_3(py)_3

Deduce the structures of [NiCl_(4)]^(2-) and [Ni (CN)_(4)]^(2-) considering the hybridisation of the metal ion. Calculate the magnetic moment (spin only) of the species.

Deduce the structures of [NiCl_(4)]^(2-) and [Ni (CN)_(4)]^(2-) considering the hybridisation of the metal ion. Calculate the magnetic moment (spin only) of the species.

CENGAGE CHEMISTRY ENGLISH-APPENDIX INORGANIC VOLUME 2-Exercises
  1. The chemistry of the actinoid elements is not so smooth as that of the...

    Text Solution

    |

  2. Which is the last element in the series of the actinoids? Write the el...

    Text Solution

    |

  3. Use Hund’s rule to derive the electronic configuration of Ce^(3+) ion,...

    Text Solution

    |

  4. Name the members of the lanthanoid series which exhibit +4 oxidation s...

    Text Solution

    |

  5. Compare the chemistry of actinoids with that of the lanthanoids with s...

    Text Solution

    |

  6. Write the electronic configurations of the elements with the atomic nu...

    Text Solution

    |

  7. Compare the general characteristics of the first series of the transit...

    Text Solution

    |

  8. Write down the number of 3d electrons in each of the following ions: ...

    Text Solution

    |

  9. Comment on the statement that elements of the first transition series ...

    Text Solution

    |

  10. What can be inferred from the magnetic moment values of the following ...

    Text Solution

    |

  11. Which of the following postulates of kinetic theory of gases is not co...

    Text Solution

    |

  12. FeSO(4) solution mixed with (NH(4))(2)SO(4) solution in 1:1 molar rati...

    Text Solution

    |

  13. Explain with two examples each of the following: coordination entity, ...

    Text Solution

    |

  14. What is meant by unidentate, didentate and ambidentate ligands? Give t...

    Text Solution

    |

  15. Specify the oxidation numbers of the metals in the following coordinat...

    Text Solution

    |

  16. Using IUPAC norms write the formulas for the following (i) Tetrahydr...

    Text Solution

    |

  17. Using IUPAC norms write the systematic names of the following: (i). ...

    Text Solution

    |

  18. List various types of isomerism possible for coordinatior compounds, g...

    Text Solution

    |

  19. How many geometrical isomers are possible in the following coordinatio...

    Text Solution

    |

  20. Draw the structures of optical isomers of: [Cr(C(2)O(4))(3)]^(3-) ...

    Text Solution

    |