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Name the members of the lanthanoid serie...

Name the members of the lanthanoid series which exhibit +4 oxidation states and those which exhibit +2 oxidation states. Try to correlate this type of behaviour with the electronic configurations of these elements.

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`Ce(58),Pr(59),Nd(60),Tb(65),Dy(66)=+4O.S`.
`Nd(60),Sm(62),Eu(63),Tm(69),Yb(70)=+2O.S`.
`+2` oxidation state is exhibited when the lanthanoid has the configuration `5d^(0)6s^(2)` so that 2 electrons are easily lost `+4` oxidation state is exhibited when the configuration left is close to `4f^(0)(e.g.4f^(0),4f^(1),4f^(2))` or close to `4f^(7)(e.g.4f^(7) or 4f^(8))`.
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CENGAGE CHEMISTRY ENGLISH-APPENDIX INORGANIC VOLUME 2-Exercises
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  2. Use Hund’s rule to derive the electronic configuration of Ce^(3+) ion,...

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  4. Compare the chemistry of actinoids with that of the lanthanoids with s...

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  5. Write the electronic configurations of the elements with the atomic nu...

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