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(a) Write the resonance structures of NO...

(a) Write the resonance structures of `NO_2^(Ө)` (nitrite) and `NO_3^(Ө)` (nitrate ion) in terms of :
(i) outer shell `overline e^, s` with formal charges
(ii) overlapping atomic orbitals.
( c) Compare the resonance (delocalisation) energy adn stabilities of `NO_2^(Ө)` and `NO_3^(Ө)`.
(b) (i) Write the resonance contributing and hybrid structures of (I) `N_2 O` (II) `H_2 C - N_2` (diazomethane).
(ii) Give the hybridised state of each atom in each structure.
(iii) Discuss their bond length in each resonance contributing structure and compare with those in hybrid structures.

Text Solution

AI Generated Solution

### Step-by-Step Solution #### (a) Resonance Structures of `NO_2^(-)` (Nitrite Ion) 1. **Draw the Lewis Structure**: - Nitrogen (N) is the central atom bonded to two oxygen (O) atoms. - One oxygen is double bonded to nitrogen, and the other is single bonded. - Assign lone pairs: The double-bonded oxygen has two lone pairs, while the single-bonded oxygen has three lone pairs and carries a negative charge. ...
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