Home
Class 11
CHEMISTRY
Giving justification, categorise the fol...

Giving justification, categorise the following molecules/ions as nucleophile or electrophile:
`HS^(-),BF_(3),C_(2)H_(5)O^(-),(CH_(3))_(3)N,`
`Coverset(+)l,CH_(3)-overset(+)C=O,H_(2)N^(-),, overset(+)NO_(2)`

Text Solution

Verified by Experts

Nucleophiles : `HS^(Ө), C_2 H_5 O^(Ө),(CH_3) _3 ddot N, overset (ddot (Ө)) N H_2`
These species have unshareped pair of `overline e^, s` which can be donated and shared with an electrophile.
Electrophilies : `BF_3, C1^(oplus), CH_3 - C^(oplus) = O, overset (oplus) NO_2`
Relative sites have only six valence `overline e^, s` and can accept `overline e` pair from a nucleophile.
Promotional Banner

Topper's Solved these Questions

  • GENERAL ORGANIC CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Comprehension|20 Videos
  • GENERAL ORGANIC CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Multiple Correct|22 Videos
  • GENERAL ORGANIC CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective|11 Videos
  • CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Analytical and Descriptive Type|3 Videos
  • HYDROGEN, WATER AND HYDROGEN PEROXIDE

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective Archive (Subjective)|3 Videos

Similar Questions

Explore conceptually related problems

Classify the following molecules/ions as nucleophiles or electrophiles HS^(-),BF_(3),CH_(3)CH_(2)O^(-),NO_(2)^(+),NH_(3),NH_(2)^(-),Cl^(+)

Categorise the following molecules/ions ad nucleophile or electrophile. (1) HS^(Ө) (2) BF_3 (3) C_2H_5O^(Ө) (4) (CH_3)_3 ddot N (5) C1^(Ө) (6) CH_3 - overset (oplus) C = O (7) :overset (Ө) NH_2 (8) overset (oplus) N O_2 .

CH_(3)-CH_(2)-CH_(2)-O-CH_(3) and CH_(3)-overset(CH_(3))overset(|)(C )H-O-CH_(3) are

The increasing order of nucleophilicity of the following nucleophiles is: (a) CH_(3)CO_(2)^(-) (b) H_(2)O (c) CH_(3)SO_(3)^(-) (d) overset(O)H

Sort out electrophiles and nucleophiles among the following overset(+)(NO_(2)), CH_(3) overset(+)(C )H_(2), AlCl_(3), C_(2)H_(5)OH, CN^(-), overset(-)(C )H_(3)

How many of the given species will behave as an electrophile? :C Cl_(2),NH_(3),overset(o+)(CH_(3)),overset(o+)(NH_(4)),overset(-)(CH_(3)),overset(-)(OH),BF_(3),AlCl_(3),overset(o+)(Br)

The increasing order of nucleophilicity of the following nucleophiles is : (a). CH_(3)CO_(2)^(ɵ) (b). H_(2)O (c). CH_(3)SO_(3)^(ɵ) (d). overset(ɵ)(O)H

Sort out electrophiles and nucleophiles among the following: CH_3 overset(+) CH_2 ,AlCl_3 ,C_2H_5 OH,CN^(-) , overset(+)CH_3 , overset(+)NO_2 ,

In the following reaction, trace the position of isotopic O^(18) CH_(3)-overset(O)overset(||)C-O-H+CH_(3)CH_(2)-overset(18)O-HhArrCH_(3)-overset(O)overset(||)C-O-CH_(2)CH_(3) +H_(2)O

CENGAGE CHEMISTRY ENGLISH-GENERAL ORGANIC CHEMISTRY-Concept
  1. Using curved-arrow notation, show the formation of reactive intermedi...

    Text Solution

    |

  2. Giving justification, categorise the following molecules/ions as nucle...

    Text Solution

    |

  3. Identify electrophilic centre in the following: CH(3)CH=O, CH(3)CN, CH...

    Text Solution

    |

  4. Which bond is more polar in the following pairs of molecules: (a) H(...

    Text Solution

    |

  5. In which C–C bond of CH(3)CH(2)CH(2)Br , the inductive effect is expec...

    Text Solution

    |

  6. Write resonance structures of CH(2)=CH–CHO . Indicate relative stabili...

    Text Solution

    |

  7. Explain why the following two structures, I and II cannot be the major...

    Text Solution

    |

  8. Explain why (CH(3))(3)overset(+)Cis more stable than CH(3)overset(+)CH...

    Text Solution

    |

  9. Draw the complete structures of bromomethane

    Text Solution

    |

  10. Which of the following pairs of structures do not constitude resonance...

    Text Solution

    |

  11. Which is expected to be more stable, (I) O2NCH2CH2O^- or (II) CH3C...

    Text Solution

    |

  12. Draw the resonance structures for the following compounds. Show the el...

    Text Solution

    |

  13. Explain why alkyl groups act as electron donors when attached to a n s...

    Text Solution

    |

  14. Classify the reagents shown in bonds in the following equations as nuc...

    Text Solution

    |

  15. Classify the following reactions in one of the reaction type studied i...

    Text Solution

    |

  16. What is the relationship between the members of following pairs of str...

    Text Solution

    |

  17. For the following bond cleavages, use curved-arrows to show the electr...

    Text Solution

    |