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Which statement is wrong ?...

Which statement is wrong ?

A

In polar aprotic solvents such as `DMSO, DMF`, and `DMA`, the fugacity order is `I^(Ө) gt Br^(Ө) gt Cl^(Ө) gt F^(Ө)`.

B

Strong bases are good leaving groups.

C

The leaving group order of the following is :
`overset (Ө) OH gt RO^(Ө) gt CH -= C^(Ө) gt overset (Ө) NH_2`.

D

Charges species are good leaving groups than neutral species.

Text Solution

Verified by Experts

The correct Answer is:
B

Weak bases are good leaving groups.
Acidic order : `H_2 O gt ROH gt CH -= CH gt NH_3`
Basic order : `overset (Ө) O H lt R O^(Ө) lt CH -= C^(Ө) lt overset (Ө) N H_2`
Weaker the base, better is the leaving group.
Leaving group order : `overset (Ө) O H gt RO^(Ө) gt CH -= C^(Ө) gt overset (Ө) N H_2`.
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CENGAGE CHEMISTRY ENGLISH-ORGANIC REACTION MECHANISM-Comprehension
  1. Which statement is wrong ?

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  2. Which statement is correct ?

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  3. The leaving group is that functional group which is ejected with overl...

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  4. The leaving group is that functional group which is ejected with overl...

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  5. The leaving group is that functional group which is ejected with overl...

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  6. The leaving group is that functional group which is ejected with overl...

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  7. Which of the following statements is wrong ?

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  8. The rate of SN^2 reaction depends on the effectiveness of the nucleoph...

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  9. The rate of SN^2 reaction depends on the effectiveness of the nucleoph...

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  10. The rate of SN^2 reaction depends on the effectiveness of the nucleoph...

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  11. Which statement is wrong in the formation of (B) from (A).

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  12. Which is correct in the formation of (C) from (A) ?

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  13. Which statement is wrong in the formation of (C) from (A) ?

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  14. In elimination reaction, the major product is either Saytzeff (more-su...

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  15. In elimination reaction, the major product is either Saytzeff (more-su...

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  16. In elimination reaction, the major product is either Saytzeff (more-su...

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  17. In elimination reaction, the major product is either Saytzeff (more-su...

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  18. Consider the following reactions : Which of the following are ste...

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  19. Consider the following reactions : Which of the following regiose...

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  20. Consider the following reactions : Syn-addition takes place in :

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