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The rate of SN^2 reaction depends on the...

The rate of `SN^2` reaction depends on the effectiveness of the nucleophile in ejecting the leaving group. Nucleophilicity is the affinity for `C` atom, while basicity is the affinity for proton.

In both cases, a new bond is formed. If a new bond is formed between the anion and proton, the specied acts as a base. If a new bond is formed between the anion and `C` atom, the species acts as nucleophile.
Which of the following is wrong ?

A

The decreasing basic order of the following is :
`NH_3 gt PH_3 gt AsH_3 gt SbH_3`

B

The decreasing basic order of the following is :
`CH_3^(Ө) gt overset (Ө) NH_2 gt overset (Ө) OH gt F^(Ө)`.

C

The decreasing nucleophilic order of the following is :
`overset (Ө)CH_3 lt overset (Ө)NH_2 lt overset (Ө) OH lt F^(Ө)`.

D

The decreasing basic and nucleophilic order of the following is :
`overset (Ө) CH_3 gt H^(Ө) gt overset (Ө) O H gt overset (Ө) O Me gt overset (Ө) CN`.

Text Solution

Verified by Experts

The correct Answer is:
C
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CENGAGE CHEMISTRY ENGLISH-ORGANIC REACTION MECHANISM-Comprehension
  1. Which of the following statements is wrong ?

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  2. The rate of SN^2 reaction depends on the effectiveness of the nucleoph...

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  3. The rate of SN^2 reaction depends on the effectiveness of the nucleoph...

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  4. The rate of SN^2 reaction depends on the effectiveness of the nucleoph...

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  5. Which statement is wrong in the formation of (B) from (A).

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  6. Which is correct in the formation of (C) from (A) ?

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  7. Which statement is wrong in the formation of (C) from (A) ?

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  8. In elimination reaction, the major product is either Saytzeff (more-su...

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  9. In elimination reaction, the major product is either Saytzeff (more-su...

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  10. In elimination reaction, the major product is either Saytzeff (more-su...

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  11. In elimination reaction, the major product is either Saytzeff (more-su...

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  12. Consider the following reactions : Which of the following are ste...

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  13. Consider the following reactions : Which of the following regiose...

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  14. Consider the following reactions : Syn-addition takes place in :

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  15. Consider the following reactions : Anti-addition takes place in :

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  16. Consider the following reactions : Meso-butan-2,3-diol is formed ...

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  17. Consider the following reactions : Racemic-butan-2,3-diol is form...

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  18. Consider the following reactions : The name of structure of MMPP ...

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  19. Consider the following reactions : Which of the following are ste...

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  20. Consider the following reactions : Which of the following regiose...

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