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Which of the compound in each of the fol...

Which of the compound in each of the following pairs will react faster in `SN^2` reaction with `overset (Ө) O H`
(A) `MeBr (I) and MeI (II)`
(B) `Me_3 C - Cl (III) and MeCl (IV)`
.

A

`overset ((A)) ((I)) overset ((B)) ((III)) overset ((C))((V))`

B

`overset ((A)) ((I)) overset ((B)) ((IV)) overset ((C))((V))`

C

`overset ((A)) ((II)) overset ((B)) ((III)) overset ((C))((VI))`

D

`overset ((A)) ((II)) overset ((B)) ((IV)) overset ((C))((VI))`

Text Solution

Verified by Experts

The correct Answer is:
D

`(A) (II), I^(Ө)` is a better leaving group than `Br^(Ө)`.
`(B)(V),I^@ RX` undergoes `SN^2` reaction than `3^@ RX`
`(A) (VI)`, Vinyl halide `(V)` does not undergo `SN^1` or `SN^2` reaction , `(VI)` is `1^@ RX`, therefore undergoes `SN^2`.
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