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Which of the following is a non-aromatic...

Which of the following is a non-aromatic compound ?

A

B

C

D

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The correct Answer is:
To determine which of the given compounds is non-aromatic, we will apply Huckel's rule of aromaticity. The key points to consider are: 1. The compound must be cyclic. 2. The compound must be planar. 3. The compound must have a conjugated system (alternating single and double bonds). 4. The compound must have an odd number of π (pi) electrons. Now, let's analyze each option step by step: ### Step 1: Analyze Option A - **Cyclic**: Yes, it is a cyclic compound. - **Planar**: No, it is non-planar. - **Conjugated**: Not applicable since it is non-planar. - **Conclusion**: Since it does not meet the planar requirement, **Option A is non-aromatic**. ### Step 2: Analyze Option B - **Cyclic**: Yes, it is a cyclic compound. - **Planar**: Yes, it is planar. - **Conjugated**: No, there is no conjugation in the ring. - **Conclusion**: Since it does not have a conjugated system, **Option B is also non-aromatic**. ### Step 3: Analyze Option C - **Cyclic**: Yes, it is a cyclic compound. - **Planar**: Yes, it is planar. - **Conjugated**: Yes, it has alternating double bonds. - **Pi Electrons**: It has an even number of π electrons (4). - **Conclusion**: Since it has an even number of π electrons, **Option C is anti-aromatic**. ### Step 4: Analyze Option D - **Cyclic**: Yes, it is a cyclic compound. - **Planar**: Yes, it is planar. - **Conjugated**: Yes, it has a conjugated system. - **Pi Electrons**: It has an odd number of π electrons (3). - **Conclusion**: Since it meets all the criteria for aromaticity, **Option D is aromatic**. ### Final Conclusion The non-aromatic compounds among the options are **Option A and Option B**. ---

To determine which of the given compounds is non-aromatic, we will apply Huckel's rule of aromaticity. The key points to consider are: 1. The compound must be cyclic. 2. The compound must be planar. 3. The compound must have a conjugated system (alternating single and double bonds). 4. The compound must have an odd number of π (pi) electrons. Now, let's analyze each option step by step: ...
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CENGAGE CHEMISTRY ENGLISH-ORGANIC REACTION MECHANISM-Single correct
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  2. Which of the following is a free radical susbtitution reaction ?

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  3. Reagent I and II, respectively, are :

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  4. Which product is racemic in the above reaction ?

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  5. Consider the following reactions.

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  6. Which of the following is a non-aromatic compound ?

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  7. The decreasing order of reactivity towards ArSN reaction of the follow...

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  8. Consider the following reaction : The product is :

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  9. Refer to Q.No. 38 and find out which of the following statements is w...

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  10. Which of the following is not a rearrangement reaction ?

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  11. Arrange the following in the reactions order of NA (nucleophilic addit...

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  12. Arrange the following in the decreasing order of nucleophilic acyl sub...

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  13. Which of the following reactions will not give Hofmann alkene ?

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  14. Which of the following is the best method for the preparation of compo...

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  15. Which statement is correct about the above reaction ?

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  16. An alkyl halide of formula C6 H13 Br on treatment with potassium t-but...

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  17. (A) and (B) are :

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  18. Which of the following reactions would give trans-alkene ? .

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  19. Which of the following reactions is Hofmann elimination ? .

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  20. Draw the structure of the following compounds: cyclopropane.

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