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Heavy metal ions Ag^+ or Pb^(2+) decreas...

Heavy metal ions `Ag^+` or `Pb^(2+)` decrease `SN^1` reactivity.
They aid ionisation of `RX`.

A

If both `(A)` and `(R )` are true, but `( R)` is the correct explanation of `(A)`

B

If both `(A)` and `( R)` are true, but `(R )` is not the correct explanation of `(A)`.

C

If `(A)` is true but `( R)` is false.

D

If `(A)` is false but `( R)` is true.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the effect of heavy metal ions like `Ag^+` or `Pb^(2+)` on `SN1` reactivity, we can break down the concepts involved step by step. ### Step-by-Step Solution: 1. **Understanding SN1 Mechanism**: - The `SN1` (Substitution Nucleophilic Unimolecular) mechanism involves two main steps: - The first step is the ionization of the alkyl halide (`RX`) to form a carbocation and a halide ion. - The second step is the nucleophilic attack on the carbocation. 2. **Role of Heavy Metal Ions**: - Heavy metal ions like `Ag^+` and `Pb^(2+)` are known to interact with halide ions. - They can stabilize the halide ion, which can facilitate the ionization of the alkyl halide. 3. **Effect on Ionization**: - When heavy metal ions are present, they can increase the ionization of the alkyl halide (`RX`). - This is because the metal ions can form complexes with the halide ions, making it easier for the halide to leave and thus promoting the formation of the carbocation. 4. **Stability of Carbocation**: - The formation of a more stable carbocation is crucial for the `SN1` mechanism. - If the ionization is facilitated, the resulting carbocation will be more stable, which in turn increases the reactivity of the `SN1` process. 5. **Conclusion**: - The assertion states that heavy metal ions decrease `SN1` reactivity, which is incorrect. - The reason states that they aid in the ionization of `RX`, which is correct. - Therefore, the correct conclusion is that the assertion is false, while the reason is true. ### Final Answer: - Assertion: False - Reason: True

To solve the question regarding the effect of heavy metal ions like `Ag^+` or `Pb^(2+)` on `SN1` reactivity, we can break down the concepts involved step by step. ### Step-by-Step Solution: 1. **Understanding SN1 Mechanism**: - The `SN1` (Substitution Nucleophilic Unimolecular) mechanism involves two main steps: - The first step is the ionization of the alkyl halide (`RX`) to form a carbocation and a halide ion. - The second step is the nucleophilic attack on the carbocation. ...
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