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ElcB reaction is favoured by stabilisati...

ElcB` reaction is favoured by stabilisation of carbanion and poor leaving group.
The reaction is kinetically of the second order and unimolecular.

A

If both `(A)` and `(R )` are true, but `( R)` is the correct explanation of `(A)`

B

If both `(A)` and `( R)` are true, but `(R )` is not the correct explanation of `(A)`.

C

If `(A)` is true but `( R)` is false.

D

If `(A)` is false but `( R)` is true.

Text Solution

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The correct Answer is:
### Step-by-Step Solution: 1. **Understanding the E1CB Reaction**: - The E1CB (unimolecular elimination via a conjugate base) reaction involves the formation of a carbanion intermediate. This reaction typically occurs when the leaving group is poor, meaning it does not easily dissociate from the molecule. 2. **Formation of Carbanion**: - In the E1CB mechanism, a base abstracts a proton (H+) from the substrate, leading to the formation of a carbanion. This step is crucial as it is the rate-determining step of the reaction. 3. **Stabilization of Carbanion**: - The stability of the carbanion is essential for the reaction to proceed. More stable carbanions will lead to a faster reaction rate. Factors that stabilize carbanions include resonance, inductive effects, and hybridization. 4. **Kinetics of the Reaction**: - The E1CB reaction is second-order because the rate depends on the concentration of both the substrate (alkyl halide) and the base. However, it is also considered unimolecular because the rate-determining step involves only the substrate and the base in the formation of the carbanion. 5. **Rate Law**: - The rate law for the E1CB reaction can be expressed as: \[ \text{Rate} = k[\text{alkyl halide}][\text{base}] \] - This indicates that the reaction rate is influenced by the concentrations of both the alkyl halide and the base. 6. **Conclusion**: - The assertion that the E1CB reaction is favored by the stabilization of the carbanion and poor leaving group is correct. The reason provided, that the reaction is second-order and unimolecular, is also correct but does not adequately explain the assertion. The correct explanation should focus on the relationship between carbanion stability and reaction rate.
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