Home
Class 11
CHEMISTRY
When a mixture of 2-merthyl propane and ...

When a mixture of 2-merthyl propane and `C C1_(4)` is reacted at 403-413 in the presence of a radical intiator, t-butyl peroxide, 2-chloro-2-methyl propane and chloroform `(CHC1_(3)` are formed. Give the mechanism of the reaction.

Text Solution

AI Generated Solution

To understand the mechanism of the reaction between 2-methylpropane and carbon tetrachloride (CCl4) in the presence of a radical initiator, we can break it down into several steps: initiation, propagation, and termination. ### Step 1: Chain Initiation 1. **Formation of Radicals**: The reaction begins with the thermal decomposition of the radical initiator, t-butyl peroxide (C4H10O2). When heated (or exposed to light), t-butyl peroxide undergoes homolytic cleavage, breaking the O-O bond to form two t-butyl radicals: \[ \text{(CH}_3\text{)}_3\text{COO-} \xrightarrow{\text{heat/light}} \text{(CH}_3\text{)}_3\text{C}^\cdot + \text{(CH}_3\text{)}_3\text{C}^\cdot \] ...
Promotional Banner

Topper's Solved these Questions

  • ALKANES AND CYCLOALKANES

    CENGAGE CHEMISTRY ENGLISH|Exercise Paragraph for problem|24 Videos
  • ALKANES AND CYCLOALKANES

    CENGAGE CHEMISTRY ENGLISH|Exercise True and False|1 Videos
  • ALKANES AND CYCLOALKANES

    CENGAGE CHEMISTRY ENGLISH|Exercise SOLVED EXAMPLES|19 Videos
  • ALKENES AND ALKADIENES

    CENGAGE CHEMISTRY ENGLISH|Exercise Single correct Answer|14 Videos

Similar Questions

Explore conceptually related problems

An alkyl halide is reduced to the corresponding alkane by tributyl stannane (C_(4)H_(9))_(3) SnH and by a free radical menchanism in the presence of an initiator, an azo compound that breaks down to N_(2) and a radical. Give the mechanism of the reaction.

Identify the product formed when propan-I ol is treated with Conc. H_(2) SO_(4) at 413 K. Write the mechanism involved for the above reaction.

What happens when propan-1-ol is treated with ethanoic acid in the presence of concentrated H_(2)SO_(4) ?

Oxidation of 2-methyl propane-1,2-diol with periodic acid gives:-

The coupling between C_2 H_5 MgBr and MeBr gives propane in the presence of :

State whether each of the following is true or false. a. Photobromination of 2-methylpropane gives a mixture of 1-bromo-2-methylpropane gives a mixture of 1-bromo-2-methylpropane and 2-bromo-2-methylpropa ne in the ratio 9 : 1 b. The percentage of n-propyl chloride obtained in the chlorination of propane is about 56% . c. The percentage of 1-chloro-2-methylpropane obtained in the chlorination of isobutane is about 64% . d. The percentage of n-propyl bromide in the bromination of propane is 44% . The relative reactives of 3^(@) , 2^(@) and 1^(@) H atoms are 1600 : 82 : 1 .

Addition of HBr to propene yields 2-bromopropane, while in the presence of benzoyl peroxide, the same reaction yields 1-bromopropane. Explain and give mechanism.

It we see the reaction of methane with halogen, the rate determining step for chlorination is, endothermic reaction of the chlorine atom with methane to form methyl radical and a molecule of HCl. So free radical is the intermediate of the reaction. Formation of free radical depends upon the energy required to break a bond between a hydrogen atom and a carbon atom. Chlorination of propane and Bromination of propane. when compared it is found that bromination is more selective than chlorination. The probability factor for 3^(@),2^(@),1^(@)H atom is 5.0:3.8:1.0 at 25^(@)C for chlorination. Isobutane when reacts with chlorine in presence of ultra violet radiations yield 2 products primary hydrogen substituted and 3^(@) hydrogen substituted Find their % in product mixture

Assertion: Addition of HBr to propene yields 2-bromopropane but in presence of a peroxide it yields 1-bromopropane. Reason: When reaction is carried out in the presence of a peroxide it follows free radical mechanism, 2^(@) free radical is more stable than 1^(@) free radical.

3-methyl-pent-2-ene on reaction with HBr in the presence of peroxide forms an addition product. The number of possible stereoisomers for the product is

CENGAGE CHEMISTRY ENGLISH-ALKANES AND CYCLOALKANES-EXERCISES
  1. a. What is the relative abstraction of H and D ? b. Why free-ra...

    Text Solution

    |

  2. There are six isomeric alkenes (A, B, C, D, E, and F) that require 1 m...

    Text Solution

    |

  3. There are five isomeric alkenes (A, B, C, D, and E) that require 1 mol...

    Text Solution

    |

  4. Write the structure of all the alkenes that can be hydrogenated to fro...

    Text Solution

    |

  5. Write the reaction of benzyl magnesium obmide with CH(3)OD and also id...

    Text Solution

    |

  6. Calculate the percentage of compounds obtained by monobromination of i...

    Text Solution

    |

  7. Which factors determine the reactivity of halogens in the subsitution ...

    Text Solution

    |

  8. Predict the percentage of ismoers formed during monobromination of 2,3...

    Text Solution

    |

  9. In the study of chlorination of propane, four prouducts A, B, C, and D...

    Text Solution

    |

  10. Chloro derivative of an organic compound 'X' on reduction with zinc-co...

    Text Solution

    |

  11. An alkyl halide is reduced to the corresponding alkane by tributyl sta...

    Text Solution

    |

  12. When a mixture of 2-merthyl propane and C C1(4) is reacted at 403-413 ...

    Text Solution

    |

  13. Alkanes are monochlorinate with t-butyl hypochlorite as a radical ...

    Text Solution

    |

  14. Delta Hc^(-) (the standard enthalpy of combustion) of butane and 2-met...

    Text Solution

    |

  15. Arrange the following compounds according to the decreasing order of h...

    Text Solution

    |

  16. Which of the following has the highest boiling point ? i. 2-Methyl ...

    Text Solution

    |

  17. How many geometrical isomers are possible for 1,2,4-Trimethyl cyclohex...

    Text Solution

    |

  18. Complete the following reaction: i. ii.

    Text Solution

    |

  19. Equal amounts of (e, e) and (a, a) conformers of trans-1,2-dichloro cy...

    Text Solution

    |

  20. Which isomer has the lower energy and which is fiexible in cis and tra...

    Text Solution

    |