Home
Class 11
CHEMISTRY
A schematic analysis of the reaction of ...

A schematic analysis of the reaction of the enantiomer with racemic mixture is shows below:
`{:(d,+,"d and l",rarr,(d)-(d)),("The(+)-form of",,"A racemic mixture of",,+),("chiral molecules",,"other molecules with",,(d)-(l)),(,,50%(d) and 50%(l),,):}`
The products (d-d) and (d-l) are clearly neither identical nor enantiomers (non-superimposable mirror images) as the diastereomers, stereoisomers that are not mirror images' . The formation of diasteromers allows the separation of enantiomers (called resolution) which is not easy as enantiomers have identical physical properties. One general with naturally occurring chiral molecule to form a pair of diastereomers. These can be separated easily as they have different physical properties. If the original chemical reaction can be reversed, the enantiomers can be isolated.
How many diastereomers are possible among all the possible stereoisomers of 2,3-dibromopentane ?

A

(a) 2

B

(b) 1

C

(c) 3

D

(d) 4

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of diastereomers possible among all the stereoisomers of 2,3-dibromopentane, we can follow these steps: ### Step 1: Identify the Stereocenters 2,3-dibromopentane has two stereocenters at the 2nd and 3rd carbon atoms. Each stereocenter can have two configurations: R (rectus) or S (sinister). ### Step 2: Calculate Total Stereoisomers The total number of stereoisomers for a compound with 'n' stereocenters is given by the formula \(2^n\). Here, \(n = 2\) (since there are two stereocenters). \[ \text{Total Stereoisomers} = 2^2 = 4 \] ### Step 3: List the Stereoisomers The four stereoisomers of 2,3-dibromopentane can be represented as follows: 1. (2R, 3R) 2. (2R, 3S) 3. (2S, 3R) 4. (2S, 3S) ### Step 4: Identify Enantiomers Enantiomers are pairs of stereoisomers that are non-superimposable mirror images of each other. From the list above: - (2R, 3R) and (2S, 3S) are enantiomers. - (2R, 3S) and (2S, 3R) are enantiomers. ### Step 5: Identify Diastereomers Diastereomers are stereoisomers that are not mirror images. From the stereoisomers listed: - (2R, 3R) and (2R, 3S) are diastereomers. - (2R, 3R) and (2S, 3R) are diastereomers. - (2R, 3S) and (2S, 3S) are diastereomers. - (2S, 3R) and (2S, 3S) are diastereomers. ### Step 6: Count the Diastereomers From the analysis, we can see that: - (2R, 3R) is a diastereomer to (2R, 3S) and (2S, 3R), and (2S, 3S). - (2R, 3S) is a diastereomer to (2R, 3R) and (2S, 3S). - (2S, 3R) is a diastereomer to (2R, 3R) and (2S, 3S). - (2S, 3S) is a diastereomer to (2R, 3R) and (2R, 3S). Thus, the total number of diastereomers is 4. ### Final Answer The number of diastereomers possible among all the possible stereoisomers of 2,3-dibromopentane is **4**. ---

To determine the number of diastereomers possible among all the stereoisomers of 2,3-dibromopentane, we can follow these steps: ### Step 1: Identify the Stereocenters 2,3-dibromopentane has two stereocenters at the 2nd and 3rd carbon atoms. Each stereocenter can have two configurations: R (rectus) or S (sinister). ### Step 2: Calculate Total Stereoisomers The total number of stereoisomers for a compound with 'n' stereocenters is given by the formula \(2^n\). Here, \(n = 2\) (since there are two stereocenters). \[ ...
Promotional Banner

Topper's Solved these Questions

  • ALKANES AND CYCLOALKANES

    CENGAGE CHEMISTRY ENGLISH|Exercise True and False|1 Videos
  • ALKANES AND CYCLOALKANES

    CENGAGE CHEMISTRY ENGLISH|Exercise Fill in the Blanks|1 Videos
  • ALKANES AND CYCLOALKANES

    CENGAGE CHEMISTRY ENGLISH|Exercise EXERCISES|24 Videos
  • ALKENES AND ALKADIENES

    CENGAGE CHEMISTRY ENGLISH|Exercise Single correct Answer|14 Videos

Similar Questions

Explore conceptually related problems

A schematic analysis of the reaction of the enantiomer with racemic mixture is shows below: {:(d,+,"d and l",rarr,(d)-(d)),("The(+)-form of",,"A racemic mixture of",,+),("chiral molecules",,"other molecules with",,(d)-(l)),(,,50%(d) and 50%(l),,):} The products (d-d) and (d-l) are clearly neither identical nor enantiomers (non-superimposable mirror images) as the diastereomers, stereoisomers that are not mirror images' . The formation of diasteromers allows the separation of enantiomers (called resolution) which is not easy as enantiomers have identical physical properties. One general with naturally occurring chiral molecule to form a pair of diastereomers. These can be separated easily as they have different physical properties. If the original chemical reaction can be reversed, the enantiomers can be isolated. Which of the following is not true ?

A schematic analysis of the reaction of the enantiomer with racemic mixture is shows below: {:(d,+,"d and l",rarr,(d)-(d)),("The(+)-form of",,"A racemic mixture of",,+),("chiral molecules",,"other molecules with",,(d)-(l)),(,,50%(d) and 50%(l),,):} The products (d-d) and (d-l) are clearly neither identical nor enantiomers (non-superimposable mirror images) as the diastereomers, stereoisomers that are not mirror images' . The formation of diasteromers allows the separation of enantiomers (called resolution) which is not easy as enantiomers have identical physical properties. One general with naturally occurring chiral molecule to form a pair of diastereomers. These can be separated easily as they have different physical properties. If the original chemical reaction can be reversed, the enantiomers can be isolated. Which of the following is an example of diastereomers ?

The stereoisomers which are superimposable mirror images of each other are called enantiomers.

Isomers which are …… mirror images are knows as ….. (superimposable, non-superimposable, enantiomers, diastereomers, epimers)

State whether the following statements are true or false. a. D and L stereoisomers are enantiomers.

In which case racemic mixture is obtained on mixing its mirror images (d & l form) is 1:1 molar ratio:

In which case racemic mixture is obtained on mixing its mirror images (d & l form) is 1:1 molar ratio:

Statement I: Molecules that are non-superimposable on their mirror images are chiral. Statement II: All chiral molecules have chiral centres.

D-Glyceraldehyde and L-Glyceraldehyde are C-2 epimers as well as enantiomers?

CENGAGE CHEMISTRY ENGLISH-ALKANES AND CYCLOALKANES-Paragraph for problem
  1. Fifteen milliliters of gaseous hydrocarbo (A) was required for complet...

    Text Solution

    |

  2. Twenty millilitres of a gaseous hydrocarbon (A) was exploded with exce...

    Text Solution

    |

  3. Twenty millilitres of a gaseous hydrocarbon (A) was exploded with exce...

    Text Solution

    |

  4. Twenty millilitres of a gaseous hydrocarbon (A) was exploded with exce...

    Text Solution

    |

  5. Twenty millilitres of a gaseous hydrocarbon (A) was exploded with exce...

    Text Solution

    |

  6. Twenty millilitres of a gaseous hydrocarbon (A) was exploded with exce...

    Text Solution

    |

  7. Twenty millilitres of a gaseous hydrocarbon (A) was exploded with exce...

    Text Solution

    |

  8. 5 " mL of " a gas A containing only C and H was mixed with an excess o...

    Text Solution

    |

  9. Five millilitires of a gas (A) containing only C and H was mixed with ...

    Text Solution

    |

  10. 5 " mL of " a gas A containing only C and H was mixed with an excess o...

    Text Solution

    |

  11. 5 " mL of " a gas A containing only C and H was mixed with an excess o...

    Text Solution

    |

  12. Five millilitires of a gas (A) containing only C and H was mixed with ...

    Text Solution

    |

  13. Five millilitires of a gas (A) containing only C and H was mixed with ...

    Text Solution

    |

  14. i. Compound (A) ii. Compound (B) iii. Alkene (C) and alkane (D) ...

    Text Solution

    |

  15. (i) Compound (A) is:- (ii) Compound (B) is:- (iii) Isomeric hexy...

    Text Solution

    |

  16. (i) Compound (A) is:- (ii) Compound (B) is:- (iii) Isomeric hexy...

    Text Solution

    |

  17. i. Compound (A) ii. Compound (B) iii. Alkene (C) and alkane (D) ...

    Text Solution

    |

  18. A schematic analysis of the reaction of the enantiomer with racemic mi...

    Text Solution

    |

  19. A schematic analysis of the reaction of the enantiomer with racemic mi...

    Text Solution

    |

  20. A schematic analysis of the reaction of the enantiomer with racemic mi...

    Text Solution

    |