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The most stable from trans-1,2-dimethyl ...

The most stable from trans-1,2-dimethyl cyclohexane is:

A

(a) (1e, 2e)

B

(b) (1a, 2a)

C

(c) (1e, 2a)

D

(d) (1a, 2e)

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The correct Answer is:
To determine the most stable form of trans-1,2-dimethylcyclohexane, we will analyze the two possible conformations: the axial and equatorial positions of the methyl groups. ### Step-by-Step Solution: 1. **Identify the Structure**: - Trans-1,2-dimethylcyclohexane has two methyl groups attached to the first and second carbon atoms of the cyclohexane ring. 2. **Understand the Conformations**: - Cyclohexane can adopt different conformations, primarily chair conformations. In these conformations, substituents can occupy axial (pointing up or down) or equatorial (pointing outwards) positions. 3. **Draw the Chair Conformation**: - Draw the chair conformation of cyclohexane and label the carbons. Place the two methyl groups on carbons 1 and 2. 4. **Analyze Axial vs. Equatorial Positions**: - **Axial Position**: If both methyl groups are in the axial position (1A, 2A), they will experience steric hindrance due to 1,3-diaxial interactions, which can destabilize the structure. - **Equatorial Position**: If both methyl groups are in the equatorial position (1E, 2E), they will be further away from each other and other hydrogen atoms on the cyclohexane ring, minimizing steric hindrance. 5. **Compare Stability**: - The equatorial conformation (1E, 2E) is more stable than the axial conformation (1A, 2A) due to reduced steric hindrance. In the axial position, the methyl groups would be closer to other axial hydrogens, leading to increased steric strain. 6. **Conclusion**: - The most stable form of trans-1,2-dimethylcyclohexane is the one where both methyl groups are in the equatorial positions (1E, 2E). ### Final Answer: The most stable form of trans-1,2-dimethylcyclohexane is the equatorial conformation (1E, 2E). ---
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CENGAGE CHEMISTRY ENGLISH-ALKANES AND CYCLOALKANES-Single Correct
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  2. Which of the following has the higest knocking property ?

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  3. Which of the following reactions will not give propane ?

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  5. The most stable confomation of cis-1,4-di-t-buty1 cyclohexane is:

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  6. The the most stable conformer of cis-cyclohexan-1,4-diol is:

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  7. The the most stable conformer of cis-cyclohexan-1,4-diol is:

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  8. The total number of isomer including stereosisomers for 1,2-dimethyl c...

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  9. The toal number of isomers including stereoisomers for 1,3- dimethyl ...

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  10. The most stable from trans-1,2-dimethyl cyclohexane is:

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  11. Consider the following reaction: Barium adipate Compound (B) is:

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  18. The structure of the compound with molecular formula C(6)H(12) that ha...

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  19. The structure of the compound with molecular formula C(8)H(14) that ha...

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