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The structure of the compound with molec...

The structure of the compound with molecular formula `C_(8)H_(14)` that has 12 secondary and 2 tertiary H atoms is:

A

(a) Bicyclo `[2.2.2]` octane

B

(b) 1,2-Dimethyl cyclohexane

C

(c) Bicyclo `[3.2.1]` octane

D

(d) Tricylo `[2.2.2.0]` octane

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To determine the structure of the compound with the molecular formula \( C_8H_{14} \) that has 12 secondary and 2 tertiary hydrogen atoms, we will analyze the options provided. ### Step 1: Understand the Definitions - **Tertiary Hydrogen**: Hydrogen atoms attached to a tertiary carbon (a carbon bonded to three other carbons). - **Secondary Hydrogen**: Hydrogen atoms attached to a secondary carbon (a carbon bonded to two other carbons). ### Step 2: Analyze Each Option #### Option A: Bicyclo[2.2.2]octane 1. **Structure**: Draw the structure of bicyclo[2.2.2]octane. 2. **Identify Tertiary Carbons**: There are 2 tertiary carbons. 3. **Count Tertiary Hydrogens**: Each tertiary carbon has 1 hydrogen, giving us 2 tertiary hydrogens. 4. **Identify Secondary Carbons**: Count the secondary carbons. 5. **Count Secondary Hydrogens**: Each secondary carbon has 2 hydrogens. There are 6 secondary carbons, resulting in \( 6 \times 2 = 12 \) secondary hydrogens. #### Conclusion for Option A: - **Tertiary Hydrogens**: 2 - **Secondary Hydrogens**: 12 - **This option is valid.** #### Option B: 1,2-Dimethylcyclohexane 1. **Structure**: Draw the structure of 1,2-dimethylcyclohexane. 2. **Identify Tertiary Carbons**: There are 2 tertiary carbons. 3. **Count Tertiary Hydrogens**: Each tertiary carbon has 1 hydrogen, giving us 2 tertiary hydrogens. 4. **Identify Secondary Carbons**: Count the secondary carbons. 5. **Count Secondary Hydrogens**: There are 4 secondary carbons, resulting in \( 4 \times 2 = 8 \) secondary hydrogens. #### Conclusion for Option B: - **Tertiary Hydrogens**: 2 - **Secondary Hydrogens**: 8 - **This option is invalid.** #### Option C: Bicyclo[3.2.1]octane 1. **Structure**: Draw the structure of bicyclo[3.2.1]octane. 2. **Identify Tertiary Carbons**: There are 2 tertiary carbons. 3. **Count Tertiary Hydrogens**: Each tertiary carbon has 1 hydrogen, giving us 2 tertiary hydrogens. 4. **Identify Secondary Carbons**: Count the secondary carbons. 5. **Count Secondary Hydrogens**: There are 6 secondary carbons, resulting in \( 6 \times 2 = 12 \) secondary hydrogens. #### Conclusion for Option C: - **Tertiary Hydrogens**: 2 - **Secondary Hydrogens**: 12 - **This option is valid.** #### Option D: Tricyclo[2.2.2.0]octane 1. **Structure**: Draw the structure of tricyclo[2.2.2.0]octane. 2. **Identify Tertiary Carbons**: There are 4 tertiary carbons. 3. **Count Tertiary Hydrogens**: Each tertiary carbon has 1 hydrogen, giving us 4 tertiary hydrogens. 4. **Identify Secondary Carbons**: Count the secondary carbons. 5. **Count Secondary Hydrogens**: This structure does not yield 12 secondary hydrogens. #### Conclusion for Option D: - **Tertiary Hydrogens**: 4 - **Secondary Hydrogens**: Not enough to meet the requirement. - **This option is invalid.** ### Final Answer: The structures that satisfy the conditions of having 12 secondary and 2 tertiary hydrogen atoms are: - **Option A: Bicyclo[2.2.2]octane** - **Option C: Bicyclo[3.2.1]octane**

To determine the structure of the compound with the molecular formula \( C_8H_{14} \) that has 12 secondary and 2 tertiary hydrogen atoms, we will analyze the options provided. ### Step 1: Understand the Definitions - **Tertiary Hydrogen**: Hydrogen atoms attached to a tertiary carbon (a carbon bonded to three other carbons). - **Secondary Hydrogen**: Hydrogen atoms attached to a secondary carbon (a carbon bonded to two other carbons). ### Step 2: Analyze Each Option ...
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CENGAGE CHEMISTRY ENGLISH-ALKANES AND CYCLOALKANES-Single Correct
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  2. Which of the following has the higest knocking property ?

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  3. Which of the following reactions will not give propane ?

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  4. Which of the following is a tetracyclic compound ?

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  5. The most stable confomation of cis-1,4-di-t-buty1 cyclohexane is:

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  6. The the most stable conformer of cis-cyclohexan-1,4-diol is:

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  7. The the most stable conformer of cis-cyclohexan-1,4-diol is:

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  8. The total number of isomer including stereosisomers for 1,2-dimethyl c...

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  9. The toal number of isomers including stereoisomers for 1,3- dimethyl ...

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  10. The most stable from trans-1,2-dimethyl cyclohexane is:

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  11. Consider the following reaction: Barium adipate Compound (B) is:

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  12. The decreasing order of boiling points of the following compounds is: ...

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  13. The decreasing order of melting points of the following compounds is: ...

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  14. The decreasing order of the acidic character of the following is: (I)

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  15. Which of the following reactions will not give four-membered cyclic co...

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  16. The structue of alkane or cycloalkane with molecular formula C(8)H(18)...

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  17. The structure of the compound with molecular formula C(6)H(12) that ha...

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  18. The structure of the compound with molecular formula C(6)H(12) that ha...

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  19. The structure of the compound with molecular formula C(8)H(14) that ha...

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  20. Give the decreasing order of the stability of the following or increas...

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