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The total number of cyclic structure as ...

The total number of cyclic structure as well as stereoisomers
possible for a compound with the molecular formula `C_(5)H_(10)` is:

A

(a) 7

B

(b) 9

C

(c) 12

D

(d) 13

Text Solution

AI Generated Solution

The correct Answer is:
To determine the total number of cyclic structures and stereoisomers for a compound with the molecular formula C₅H₁₀, we can follow these steps: ### Step 1: Determine the Degree of Unsaturation The degree of unsaturation (DU) can be calculated using the formula: \[ DU = \frac{2C + 2 - H}{2} \] Where \(C\) is the number of carbon atoms and \(H\) is the number of hydrogen atoms. For C₅H₁₀: \[ DU = \frac{2(5) + 2 - 10}{2} = \frac{10 + 2 - 10}{2} = \frac{2}{2} = 1 \] This means there is one degree of unsaturation, indicating the presence of either a ring or a double bond. ### Step 2: Identify Possible Cyclic Structures With one degree of unsaturation, we can have cyclic structures. For five carbon atoms, we can form: - A **cyclopentane** (5-membered ring). - A **cyclobutane** (4-membered ring) with a methyl group attached. - A **cyclopropane** (3-membered ring) with two methyl groups attached. ### Step 3: Draw and Count the Isomers 1. **Cyclopentane**: This is a single structure. 2. **Cyclobutane with Methyl Group**: The methyl group can be attached in different positions, but due to symmetry, they are not unique. This gives us one unique isomer. 3. **Cyclopropane with Two Methyl Groups**: The two methyl groups can be positioned either on adjacent carbons (cis) or on opposite carbons (trans). This gives us two unique isomers. ### Step 4: Count the Total Cyclic Structures From the above: - 1 (Cyclopentane) - 1 (Cyclobutane with a methyl group) - 2 (Cyclopropane with two methyl groups) Total cyclic structures = \(1 + 1 + 2 = 4\) ### Step 5: Identify Stereoisomers Now, we need to consider stereoisomers: - For the cyclopropane with two methyl groups, we have cis and trans forms, which are stereoisomers. - The cyclobutane with a methyl group can also exhibit stereoisomerism depending on the orientation of the methyl group. ### Step 6: Total Count of Isomers Combining all the isomers: - Cyclopentane: 1 - Cyclobutane: 1 - Cyclopropane (cis and trans): 2 Thus, the total number of isomers (including stereoisomers) is: \[ 1 + 1 + 2 = 4 \] ### Final Answer The total number of cyclic structures and stereoisomers possible for a compound with the molecular formula C₅H₁₀ is **4**. ---

To determine the total number of cyclic structures and stereoisomers for a compound with the molecular formula C₅H₁₀, we can follow these steps: ### Step 1: Determine the Degree of Unsaturation The degree of unsaturation (DU) can be calculated using the formula: \[ DU = \frac{2C + 2 - H}{2} \] Where \(C\) is the number of carbon atoms and \(H\) is the number of hydrogen atoms. ...
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