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In the following sequence of reactions, ...

In the following sequence of reactions, the products (A) to (G) are formed:
i. `2CH_4(g)overset(Delta)underset(1773K)rarr(A)(g)+B(g)`
ii. `4 mol of (A) overset(Delta)underset(Ni(CN)_4+THF)rarr(C)overset(O_3//o x id.)rarr(D) only`
iii. `(A)overset((1) 1 mol of NaNH_2)underset((2) C_2H_5I)rarr(E)underset(Red hot tube)overset(3 mol of E)rarrunderset((G) only)underset(darr O_3//Red.)F`
Compounds G is

A

2-Oxobutanal

B

2-Oxobutanoic acid

C

Methylglyoxal

D

2-Oxopropanoic acid

Text Solution

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The correct Answer is:
To determine the compound G formed in the sequence of reactions, we will analyze each step systematically. ### Step 1: Identify Compound A In the first reaction, we have: \[ 2 CH_4(g) \overset{\Delta}{\rightarrow} (A)(g) + B(g) \] When two moles of methane (CH₄) are heated to a high temperature (1773 K), they can decompose to form ethyne (C₂H₂) and hydrogen gas. Thus, compound A is: \[ A = C_2H_2 \text{ (ethyne)} \] ### Step 2: Identify Compound C Next, we have: \[ 4 \text{ mol of } (A) \overset{\Delta}{\underset{Ni(CN)_4 + THF}{\rightarrow}} C \] When ethyne (C₂H₂) is treated with nickel tetracarbonyl (Ni(CN)₄) in tetrahydrofuran (THF), it can undergo a reaction to form a compound that is likely a diene. The exact structure of compound C is not specified, but it is an intermediate formed from the reaction of ethyne. ### Step 3: Identify Compound E Now, we look at the reaction: \[ (A) \overset{(1) 1 \text{ mol of } NaNH_2}{\underset{(2) C_2H_5I}{\rightarrow}} E \] Here, ethyne (C₂H₂) reacts with sodium amide (NaNH₂) to form a carbon anion, which then attacks ethyl iodide (C₂H₅I) in an SN2 reaction. This results in the formation of: \[ E = CH_3CH_2C \equiv CH \text{ (1-butyne)} \] ### Step 4: Identify Compound F Next, we have: \[ \text{(3 mol of E) } \overset{\text{Red hot tube}}{\rightarrow} F \] When 1-butyne (C₄H₆) is subjected to high temperatures in a red hot tube, it can undergo rearrangement to form a more stable compound, likely leading to: \[ F = C_6H_6 \text{ (benzene)} \] ### Step 5: Identify Compound G Finally, we have: \[ F \overset{O_3 // \text{Red.}}{\rightarrow} G \] When benzene (C₆H₆) is treated with ozone (O₃) followed by reduction, it typically leads to the formation of carbonyl compounds. In this case, it can yield: \[ G = 2-oxo butanol \text{ (C₄H₈O₂)} \] ### Conclusion Thus, the compound G formed in the sequence of reactions is: \[ G = 2-oxo butanol \]

To determine the compound G formed in the sequence of reactions, we will analyze each step systematically. ### Step 1: Identify Compound A In the first reaction, we have: \[ 2 CH_4(g) \overset{\Delta}{\rightarrow} (A)(g) + B(g) \] When two moles of methane (CH₄) are heated to a high temperature (1773 K), they can decompose to form ethyne (C₂H₂) and hydrogen gas. Thus, compound A is: \[ A = C_2H_2 \text{ (ethyne)} \] ...
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CENGAGE CHEMISTRY ENGLISH-ALKYNES-Exercises (Linked Comprehension Type)
  1. In the following sequence of reactions, products (B) to (E) are formed...

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  2. In the following sequence of reactions, products (B) to (E) are formed...

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  3. Select the correct statements:

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  4. In the following sequence of reactions, the products (A) to (G) are fo...

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  5. In the following sequence of reactions, the products (A) to (G) are fo...

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  6. In the following sequence of reactions, the products (A) to (G) are fo...

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  7. In the following sequence of reactions, the products (A) to (G) are fo...

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  8. In the following sequence of reactions, the products (A) to (G) are fo...

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  9. In the following sequence of reactions, the products (A) to (G) are fo...

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  10. Draw Organic Structure of ethane

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  11. Draw the Structure of Propane Which is 3rd member of alkane family

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  12. Draw the Structure of butane Which is 4th member of alkane family

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  13. Compound CH3CH2OH is:

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  14. Draw the Structure for Ethanol

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  15. The suffix in ethanol is used to Define Which functional Group

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  16. In the following sequence of reactions, products A to D are formed: ...

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  17. In the following sequence of reactions, products A to D are formed: ...

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  18. In the following sequence of reactions, products A to D are formed: ...

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  19. In the following sequence of reactions, products B to E are formed: ...

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  20. In the following sequence of reactions, products B to E are formed: ...

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