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Which of the following statement(s) is/a...

Which of the following statement(s) is/are correct:

A

(a) Hydrogenation of but-2-yne in the presence of Lindlar's catalyst yields cis-but-2-ene.

B

(b) Hydrogenation of pent-2-yne in the presence of P-2 catalyst yields trans-pent-2-ene.

C

(c) Hydrogenation of pent-2-yne in the presence of K (potassium) and liquid `NH_3` yields trans-pent-2-ene.

D

(d) Hydrogenation of but-2-yne in the presence of `LiAlH_4` yields cis-but-2-ene.

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The correct Answer is:
To determine which of the statements regarding the hydrogenation of alkynes are correct, we will analyze each statement step by step. ### Step 1: Analyze Statement A **Statement A:** Hydrogenation of but-2-yne in the presence of Lindlar's catalyst yields cis-but-2-ene. - **Hydrogenation Process:** But-2-yne (C4H6) can be hydrogenated using Lindlar's catalyst, which is a poisoned palladium catalyst. This catalyst facilitates the addition of hydrogen (H2) to the triple bond of but-2-yne, resulting in the formation of a cis-alkene. - **Product Formation:** The product formed will have both methyl groups on the same side, resulting in cis-but-2-ene. **Conclusion for Statement A:** This statement is correct. ### Step 2: Analyze Statement B **Statement B:** Hydrogenation of pent-2-yne in the presence of Pt catalyst yields trans-pent-2-ene. - **Hydrogenation Process:** Pent-2-yne (C5H8) can be hydrogenated using a platinum (Pt) catalyst. However, platinum is a non-poisoned catalyst that allows for syn addition, leading to the formation of a cis-alkene. - **Product Formation:** The product formed will be cis-pent-2-ene, not trans-pent-2-ene. **Conclusion for Statement B:** This statement is incorrect. ### Step 3: Analyze Statement C **Statement C:** Hydrogenation of pent-2-yne in the presence of K (potassium) and liquid NH3 yields trans-pent-2-ene. - **Hydrogenation Process:** When pent-2-yne is hydrogenated in the presence of potassium and liquid ammonia, this reaction leads to anti-addition of hydrogen across the triple bond. - **Product Formation:** The product formed will be trans-pent-2-ene. **Conclusion for Statement C:** This statement is correct. ### Step 4: Analyze Statement D **Statement D:** Hydrogenation of but-2-yne in the presence of NiAlH4 yields cis-but-2-ene. - **Hydrogenation Process:** But-2-yne can be hydrogenated using NiAlH4, which is a strong reducing agent. However, this reaction typically leads to the formation of a trans-alkene due to the nature of the addition. - **Product Formation:** The product formed will be trans-but-2-ene, not cis-but-2-ene. **Conclusion for Statement D:** This statement is incorrect. ### Final Conclusion - **Correct Statements:** A and C are correct. - **Incorrect Statements:** B and D are incorrect. ### Summary of Correct Statements: - Statement A: Correct - Statement B: Incorrect - Statement C: Correct - Statement D: Incorrect

To determine which of the statements regarding the hydrogenation of alkynes are correct, we will analyze each statement step by step. ### Step 1: Analyze Statement A **Statement A:** Hydrogenation of but-2-yne in the presence of Lindlar's catalyst yields cis-but-2-ene. - **Hydrogenation Process:** But-2-yne (C4H6) can be hydrogenated using Lindlar's catalyst, which is a poisoned palladium catalyst. This catalyst facilitates the addition of hydrogen (H2) to the triple bond of but-2-yne, resulting in the formation of a cis-alkene. - **Product Formation:** The product formed will have both methyl groups on the same side, resulting in cis-but-2-ene. ...
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  4. For the conversion of alkyne to cis-alkene, H2+ Lindlar's catalyst is ...

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  5. i. Me--=-Hunderset((ii)H2O2//overset(Ө)OH)overset((i) Sia2BH)rarrA i...

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  8. Compound (B) is same when (A) is:

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  9. Which of the statements are correct? R--=-R^'underset(+EtOH)overset(...

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  10. Which of the statements are correct? R--=-Runderset(Catalyst)overset...

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  12. C4H6underset(1 mol)overset(H2+Pt)rarrC4H8overset(O3//H2O)rarr Acedic a...

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  14. Compound (A) does not react with Tollens or Grignard reagent, but afte...

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  15. Compound (A) reacts with [Cu(NH3)2]^(+) and Tollens reagent, but after...

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  17. Reagents used in conversion from (A) to (B) are:

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  18. Which gas is in an antidote of Lewisite (a poisonous gas used in World...

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  20. Which statements are correct for reagents A, B, C, and D?

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