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2H--=-Hunderset(NH4Cl)overset(CuCl)rarrA...

`2H--=-Hunderset(NH_4Cl)overset(CuCl)rarrAoverset(H_2+Ni_2B)rarrBunderset((Majo r))overset(Br_2)rarrC`
The major amount of (C) is:

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reactions described in the question. ### Step 1: Identify the starting material We start with 2 moles of acetylene (C2H2). ### Step 2: Reaction with CuCl and NH4Cl When 2 moles of acetylene react in the presence of CuCl and NH4Cl, they undergo a process known as linear polymerization. This reaction leads to the formation of vinyl acetylene. **Chemical Reaction:** \[ 2 \text{C}_2\text{H}_2 \xrightarrow{\text{CuCl, NH}_4\text{Cl}} \text{C}_4\text{H}_4 \text{ (vinyl acetylene)} \] **Structure of Vinyl Acetylene:** \[ \text{C} \equiv \text{C}-\text{C}=\text{C}-\text{H} \] ### Step 3: Hydrogenation of Vinyl Acetylene Next, the vinyl acetylene (A) undergoes hydrogenation in the presence of hydrogen (H2) and a nickel-boron catalyst (Ni2B). This reaction adds hydrogen across the double bond. **Chemical Reaction:** \[ \text{C}_4\text{H}_4 + \text{H}_2 \xrightarrow{\text{Ni}_2\text{B}} \text{C}_4\text{H}_6 \text{ (B)} \] ### Step 4: Bromination of the Hydrogenated Product The product from the hydrogenation (B) is then treated with bromine (Br2). This reaction typically leads to the addition of bromine across the double bond, specifically following Markovnikov's rule, which results in 1,4-addition. **Chemical Reaction:** \[ \text{C}_4\text{H}_6 + \text{Br}_2 \rightarrow \text{C}_4\text{H}_6\text{Br}_2 \text{ (C)} \] ### Step 5: Identify the Major Product (C) The major product (C) formed from the bromination will have the structure where bromine atoms are added at the 1 and 4 positions of the double bond. **Structure of Major Product (C):** \[ \text{Br}-\text{C}-\text{C}=\text{C}-\text{Br} \] ### Conclusion The major product (C) formed from the reactions is a dibromide compound, specifically 1,4-dibromo-2-butene. ### Final Answer The major amount of (C) is 1,4-dibromo-2-butene. ---

To solve the problem step by step, we will analyze the reactions described in the question. ### Step 1: Identify the starting material We start with 2 moles of acetylene (C2H2). ### Step 2: Reaction with CuCl and NH4Cl When 2 moles of acetylene react in the presence of CuCl and NH4Cl, they undergo a process known as linear polymerization. This reaction leads to the formation of vinyl acetylene. ...
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