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Acidic hydrogen is present in:...

Acidic hydrogen is present in:

A

(a) Ethyne

B

(b) Ethene

C

(c) Benzene

D

(d) Ethane

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound has acidic hydrogen, we need to analyze the structures of the given options and understand the concept of acidic hydrogen. Acidic hydrogen is defined as a hydrogen atom that can be removed from a molecule, resulting in a stable negative charge (conjugate base). ### Step-by-Step Solution: 1. **Identify the Compounds**: - A) Ethane (C2H6) - B) Ethene (C2H4) - C) Benzene (C6H6) - D) Ethyne (C2H2) 2. **Draw the Structures**: - Ethane: CH3-CH3 - Ethene: CH2=CH2 - Benzene: C6H6 (ring structure with alternating double bonds) - Ethyne: HC≡CH 3. **Understand Acidic Hydrogen**: - Acidic hydrogen is one that can be removed to form a stable conjugate base. The stability of the conjugate base is influenced by the hybridization of the carbon atom to which the hydrogen is attached. - The order of acidity based on hybridization is: sp > sp2 > sp3. This means that hydrogen attached to sp hybridized carbon is the most acidic. 4. **Analyze Each Compound**: - **Ethane (C2H6)**: All hydrogens are attached to sp3 hybridized carbons. Removal of a hydrogen would result in a highly unstable negative charge on an sp3 carbon. Thus, it does not have acidic hydrogen. - **Ethene (C2H4)**: The hydrogen is attached to sp2 hybridized carbons. Removal of a hydrogen would result in a negative charge on an sp2 carbon, which is more stable than sp3 but less than sp. - **Benzene (C6H6)**: The hydrogens are attached to sp2 hybridized carbons. Similar to ethene, removal of a hydrogen would result in a negative charge on an sp2 carbon. - **Ethyne (C2H2)**: The hydrogen is attached to sp hybridized carbons. Removal of a hydrogen would result in a negative charge on an sp carbon, which is the most stable. 5. **Conclusion**: - The compound that has acidic hydrogen is **Ethyne (C2H2)**, as it has sp hybridized carbons, making the hydrogen attached to it the most acidic. ### Final Answer: The correct option is **D) Ethyne**.

To determine which compound has acidic hydrogen, we need to analyze the structures of the given options and understand the concept of acidic hydrogen. Acidic hydrogen is defined as a hydrogen atom that can be removed from a molecule, resulting in a stable negative charge (conjugate base). ### Step-by-Step Solution: 1. **Identify the Compounds**: - A) Ethane (C2H6) - B) Ethene (C2H4) - C) Benzene (C6H6) ...
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