Home
Class 12
CHEMISTRY
Hexan-3-one can be obtained by the react...

Hexan-3-one can be obtained by the reaction of `EtMgBr` and.

A

Butanamide

B

Propanamide

C

Butane nitrile

D

Propane nitrile

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound can react with ethyl magnesium bromide (EtMgBr) to yield hexan-3-one, we need to analyze the reaction mechanism of Grignard reagents with carbonyl compounds and nitriles. ### Step-by-Step Solution: 1. **Identify the Structure of Hexan-3-one**: Hexan-3-one is a ketone with the structure CH3-CO-CH2-CH2-CH3. The carbonyl group (C=O) is located at the third carbon in a six-carbon chain. 2. **Understand the Role of Grignard Reagents**: Grignard reagents, such as EtMgBr, are nucleophiles that can attack electrophilic carbonyl carbon atoms. The ethyl group (C2H5-) from EtMgBr will add to the carbonyl carbon of a suitable electrophile. 3. **Consider Possible Electrophiles**: To form hexan-3-one, we need a compound that can provide the necessary carbon skeleton. The options given are butanamide, propanamide, nitriles, and propanenitrile. 4. **Reacting with Butanamide**: - Butanamide (CH3CH2CH2C(=O)NH2) has a carbonyl group that can react with EtMgBr. - The reaction will yield an intermediate where the ethyl group attaches to the carbonyl carbon, resulting in a compound that can be hydrolyzed to form hexan-3-one. 5. **Hydrolysis of the Intermediate**: - The intermediate formed after the reaction with butanamide will look like this: CH3CH2CH2C(OH)(C2H5)NH2. - Upon hydrolysis, the amine group will be converted to an alcohol, and the product will be hexan-3-one (CH3-CO-CH2-CH2-CH3) along with ammonia and magnesium bromide byproducts. 6. **Conclusion**: - The reaction of ethyl magnesium bromide with butanamide leads to the formation of hexan-3-one upon hydrolysis. - Therefore, the answer to the question is **butanamide**.

To determine which compound can react with ethyl magnesium bromide (EtMgBr) to yield hexan-3-one, we need to analyze the reaction mechanism of Grignard reagents with carbonyl compounds and nitriles. ### Step-by-Step Solution: 1. **Identify the Structure of Hexan-3-one**: Hexan-3-one is a ketone with the structure CH3-CO-CH2-CH2-CH3. The carbonyl group (C=O) is located at the third carbon in a six-carbon chain. 2. **Understand the Role of Grignard Reagents**: ...
Promotional Banner

Topper's Solved these Questions

  • GRIGNARD REAGENTS AND ORGANOMETALLIC REAGENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Single Correct)|47 Videos
  • GRIGNARD REAGENTS AND ORGANOMETALLIC REAGENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Single Correct)|4 Videos
  • GRIGNARD REAGENTS AND ORGANOMETALLIC REAGENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Linked Comprehension)|33 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Subjective)|14 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY ENGLISH|Exercise Nuclear Chemistry (NCERT Exercise)|29 Videos

Similar Questions

Explore conceptually related problems

Acetophenone can be obtained by the reaction of PhMgBr and.

Boron can be obtained by:

Acetylene can be obtained by the reaction

A 3^@ alcohol can be obtained by the reaction of PhMgBr and.

PH_(3) can be obtained by:

Cyanogen gas is obtained in the reaction

Ethylamine can be obtaine by

Chloropicrin is obtained by the reaction of