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Which of the following reactions would g...

Which of the following reactions would give `pentan-2-ol` ?

A

B

C

D

`MeCHO overset(PrmgBr//ether) underset (H_3 O^(oplus))rarr`

Text Solution

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The correct Answer is:
To determine which of the given reactions would yield pentan-2-ol, we need to analyze each option step by step. Pentan-2-ol has the following structure: ``` CH3 | CH3-CH-CH2-CH3 | OH ``` This indicates that the hydroxyl group (-OH) is attached to the second carbon of a five-carbon chain (pentane). ### Step 1: Analyze Each Option **Option 1:** - The reaction involves a Grignard reagent (R-MgBr) reacting with a carbonyl compound (ketone or aldehyde). - If we assume the carbonyl compound is a ketone like butan-2-one (CH3-CO-CH2-CH3), the Grignard reagent (e.g., CH3MgBr) adds to the carbonyl carbon, forming a tertiary alcohol after hydrolysis. - The final product will be pentan-2-ol. **Option 2:** - Similar to Option 1, if we use a Grignard reagent with a different carbonyl compound, such as propan-2-one (CH3-CO-CH3), and add CH3MgBr, we can also form pentan-2-ol after hydrolysis. - The reaction will yield pentan-2-ol as well. **Option 3:** - In this case, if we start with a compound like 1-bromopropane (CH3-CH2-CH2-Br) and react it with a Grignard reagent (e.g., CH3MgBr), the product after hydrolysis will also yield pentan-2-ol. - The mechanism involves the formation of a new carbon-carbon bond, leading to the desired alcohol. **Option 4:** - Here, if we start with a carbonyl compound like butanal (CH3-CH2-CHO) and react it with a Grignard reagent, we can also achieve pentan-2-ol. - The addition of the Grignard reagent to the carbonyl, followed by hydrolysis, will yield pentan-2-ol. ### Conclusion All four options can lead to the formation of pentan-2-ol through different pathways involving Grignard reagents and appropriate carbonyl compounds. ### Final Answer All options (1, 2, 3, and 4) would give pentan-2-ol. ---

To determine which of the given reactions would yield pentan-2-ol, we need to analyze each option step by step. Pentan-2-ol has the following structure: ``` CH3 | CH3-CH-CH2-CH3 | OH ...
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