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The end product ( C) of the following se...

The end product `( C)` of the following sequence of reaction is :
`CH -= CH + MeMgBr (1 mol) rarr (A) overset ((i) CO_2) underset((ii)H_3 O^(oplus))rarr (B) overset (HgSO_4//H_2 SO_4)rarr (C)`.

A

B

C

D

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The correct Answer is:
To determine the end product (C) of the given sequence of reactions, we will analyze each step carefully. ### Step 1: Reaction of Acetylene with Grignard Reagent The first step involves the reaction of acetylene (CH≡CH) with methyl magnesium bromide (MeMgBr). - **Reaction**: \[ \text{CH} \equiv \text{CH} + \text{MeMgBr} \rightarrow \text{C} \equiv \text{C} \text{MgBr} + \text{CH}_4 \] - **Product (A)**: The product formed is a magnesium alkynide, which can be represented as C≡C-MgBr. ### Step 2: Reaction of Product A with Carbon Dioxide Next, product A reacts with carbon dioxide (CO₂) in an acidic medium. - **Reaction**: \[ \text{C} \equiv \text{C} \text{MgBr} + \text{CO}_2 \xrightarrow{\text{H}^+} \text{RCOOMgBr} \rightarrow \text{RCOOH} \] - **Product (B)**: This reaction leads to the formation of a carboxylic acid (RCOOH), where R is the alkyl group from the Grignard reagent. In this case, it will be acetic acid (CH₃COOH). ### Step 3: Reaction of Product B with Acid The next step involves the reaction of product B (the carboxylic acid) with sulfuric acid (H₂SO₄). - **Reaction**: \[ \text{CH}_3\text{COOH} \xrightarrow{\text{H}_2\text{SO}_4} \text{C} = \text{C} \text{(OH)} \text{(unstable alkenol)} \] - **Product**: This reaction leads to the formation of an alkenol, which is an unstable compound. ### Step 4: Tautomerization of Alkenol The unstable alkenol undergoes tautomerization to form a more stable ketone. - **Reaction**: \[ \text{C} = \text{C} \text{(OH)} \rightarrow \text{C} = \text{O} \text{(C)} \text{COOH} \] - **Final Product (C)**: The final product is a ketone, specifically 3-oxobutanoic acid (or acetoacetic acid). ### Conclusion The end product (C) of the sequence of reactions is **3-oxobutanoic acid** or **acetoacetic acid**.

To determine the end product (C) of the given sequence of reactions, we will analyze each step carefully. ### Step 1: Reaction of Acetylene with Grignard Reagent The first step involves the reaction of acetylene (CH≡CH) with methyl magnesium bromide (MeMgBr). - **Reaction**: \[ \text{CH} \equiv \text{CH} + \text{MeMgBr} \rightarrow \text{C} \equiv \text{C} \text{MgBr} + \text{CH}_4 ...
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