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Benzonitrile on reaction with C2 H5 MgBr...

Benzonitrile on reaction with `C_2 H_5 MgBr`, followed by hydrolysis, gives.

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B

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To solve the problem of what product is formed when benzonitrile reacts with ethyl magnesium bromide followed by hydrolysis, we can break it down into several steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - Benzonitrile (C6H5CN) - Ethyl magnesium bromide (C2H5MgBr) ### Step 2: Understand the Reaction Mechanism Benzonitrile contains a cyano group (–C≡N) which is polarized due to the electronegativity of nitrogen. The carbon atom in the cyano group is electrophilic, making it susceptible to nucleophilic attack. ### Step 3: Nucleophilic Attack The ethyl group (C2H5–) from ethyl magnesium bromide acts as a nucleophile. It attacks the electrophilic carbon of the cyano group in benzonitrile. The reaction can be represented as follows: \[ \text{C}_6\text{H}_5\text{C} \equiv \text{N} + \text{C}_2\text{H}_5\text{MgBr} \rightarrow \text{C}_6\text{H}_5\text{C}(\text{C}_2\text{H}_5)\text{N} \text{MgBr} \] ### Step 4: Formation of the Intermediate The product of this nucleophilic attack is an intermediate compound where the cyano group is now attached to the ethyl group, forming a compound with a carbon-nitrogen bond and a magnesium bromide ion: \[ \text{C}_6\text{H}_5\text{C}(\text{C}_2\text{H}_5)\text{N} \text{MgBr} \] ### Step 5: Hydrolysis of the Intermediate Upon hydrolysis, the intermediate reacts with water. The magnesium bromide part is removed, and the cyano group is converted to a carbonyl group (–C=O), resulting in the formation of an imine which then hydrolyzes to form a ketone. The final product after hydrolysis is: \[ \text{C}_6\text{H}_5\text{C}(\text{C}_2\text{H}_5)=\text{O} \] This compound is **ethyl phenyl ketone**, also known as **acetophenone**. ### Conclusion Thus, the final product formed when benzonitrile reacts with ethyl magnesium bromide followed by hydrolysis is **acetophenone (C6H5C(O)C2H5)**.

To solve the problem of what product is formed when benzonitrile reacts with ethyl magnesium bromide followed by hydrolysis, we can break it down into several steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - Benzonitrile (C6H5CN) - Ethyl magnesium bromide (C2H5MgBr) ### Step 2: Understand the Reaction Mechanism ...
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Knowledge Check

  • Cumene on reaction with oxygen followed by hydrolysis gives

    A
    `CH_(3)OH` and `C_(6)H_(5)COCH_(3)`
    B
    `C_(6)H_(5)OH and (CH_(3))_(2)O`
    C
    `C_(6)H_(5)OCH_(3)` and `CH_(3)OH`
    D
    `C_(6)H_(5)OH` and `CH_(3)COCH_(3)`
  • CENGAGE CHEMISTRY ENGLISH-GRIGNARD REAGENTS AND ORGANOMETALLIC REAGENTS-Exercises (Single Correct)
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    2. Methyl oxirane on reaction with CH3 MgBr, followed by hydrolysis, give...

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    3. Benzonitrile on reaction with C2 H5 MgBr, followed by hydrolysis, give...

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    4. Acetoisonitrile on reaction with C2 H5 MgBr followed by hydrolysis, gi...

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    5. .

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    8. .

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    9. Ethanoic propanoic anhydride on reaction with excess of MeMgBr gives t...

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    10. Reactivity of MeMgBr with the following in the decreasing order is : ...

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    11. Product. The major product is :

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    12. Reactivity of with the following G.R in the decreasing order is : (...

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    13. .

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    14. Reactivity of EtMgBr with the following in the decreasing order is : ...

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    16. Reactivity of PhMgBr with the following in the decreasing order is : ...

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    19. Ethyl ester reacts with PrMgBr to give 2^@ alcohol. The alcohol is :

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