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Identify A, B, and C, i. Isomeric alc...

Identify A, B, and C,
i. Isomeric alcohols (A), (B), and (C) `(C_(5)H_(12)O)`.
ii. (A) and (B) react with chromic acid solution. (B) gives an acid (D).
iii. Reactivity with HBr is `C gt A gtgt B` . All give the same compound, `C_(5)H_(11)Br` (E).
iv. Only (A) is oxidised by NaOI.

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i. Zero DU in all alcohols suggests the absence of ring or `(C=C)` or `(C-=C)` bond.
ii. `overset ((B)) underset (ROH)` `overset (H_(2)CrO_(4)) rarr` Acid (D) suggests that (B) is `1^(@)`
`overset ((A)) underset (ROH)` `overset (H_(2)CrO_(4)) rarr` No acid suggests that (A) is `2^(@)`
iii. Reactivity with HBr suggests, (C) is `3^(@)` ROH. Reaction of (A) with NaOI (Iodoform test) suggests. `(R-underset(OH)underset(|)(C )H-CH_(3))` type of alcohol.
(A), (B), and (C) `overset (HBr) rarr` Same `C_(5)H_(11)Br` (E) suggests that rearrangement is taking place by `H^(-)` or Me shift.
iv. `overset ([O]) underset (H_(2)CrO_(4) rarr` No reaction
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CENGAGE CHEMISTRY ENGLISH-ALCOHOL,PHENOL AND ETHERS-Exercises Subjective
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  2. Identify A, B, and C, i. Isomeric alcohols (A), (B), and (C) (C(5)H...

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  3. Identify (A)

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  4. C(7)H(14) (A) decolourises Br(2) in C CI(4) and reacts with Hg(OAc)(2)...

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  5. Compound (D), an isomer of (A) in Problem 4, reacts with BH(3). THF an...

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  6. Compound (A), C(8)H(6)NOBr, is optically active. Reduction of (A) give...

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  7. Identify A to E.

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  8. An organic compound (A) (C(8)H(8)O(3)) was insoluble in water, dilute ...

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  10. Find the structure of (A), C(10)H(10)O(2), a sweet-smelling liquid tha...

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  13. An organic compound (A) gives opsitive Liebermann reaction and on trea...

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  14. Two isomeric compounds, (A) and (B), have the same formula, C(11)H(13)...

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