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Compound (A), C(8)H(6)NOBr, is optically...

Compound (A), `C_(8)H_(6)NOBr`, is optically active. Reduction of (A) gives (B) which reacts with nitrouos acid to form (C), dihydric alcohol. Benzene sulphonyl chloride reacts with (B) to give a product soluble in NaOH. Hydrolysis of (A) gives (D) which is an optically active acid. (A) does not give any precipitate with aqueous `AgNO_(3)` . Controlled oxidation of (A) gives monobromo benzoic acid. Compound (A) on reaction with `Br_(2)//Fe` gives only one compound. Identify (A), (B), (C), and (D).

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To solve the question step by step, we will identify the compounds A, B, C, and D based on the information provided. ### Step 1: Analyze Compound A Given the molecular formula of compound A as `C8H6NOBr`, we calculate the degree of unsaturation (DU) to understand its structure. **Degree of Unsaturation Calculation:** Using the formula: \[ \text{DU} = \frac{(2n_C + 2 - n_H + n_X - n_N)}{2} \] ...
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CENGAGE CHEMISTRY ENGLISH-ALCOHOL,PHENOL AND ETHERS-Exercises Subjective
  1. C(7)H(14) (A) decolourises Br(2) in C CI(4) and reacts with Hg(OAc)(2)...

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  2. Compound (D), an isomer of (A) in Problem 4, reacts with BH(3). THF an...

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  3. Compound (A), C(8)H(6)NOBr, is optically active. Reduction of (A) give...

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  4. Identify A to E.

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  5. An organic compound (A) (C(8)H(8)O(3)) was insoluble in water, dilute ...

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  6. Neutralisation of 30 gm of a mixture of acetic acid and phenol solutio...

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  7. Find the structure of (A), C(10)H(10)O(2), a sweet-smelling liquid tha...

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  8. a. Isomers (A) and (B), C(10)H(12)O, are isolated form the oil of bay...

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  9. An aromatic compound (A), C(7)H(5)NO(2)CI(2) on reduction with Sn//HCI...

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  10. An organic compound (A) gives opsitive Liebermann reaction and on trea...

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  11. Two isomeric compounds, (A) and (B), have the same formula, C(11)H(13)...

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  12. Nirtobenzene is formed as the major product along with a minor product...

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  13. Identify A, B, and C, in the following reaction.

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  14. Provide a mechanism for the products (A) and (B). Which one will be th...

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  15. Identify the substances (A) through (D) in a sequence. Comment on...

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  16. Identify each of the following glucose derivative. a. A+5HIO(4)rarr...

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  17. If is treated with alkaline NaN(3) and followed by reduction with H(2...

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  18. Converst

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  19. Assign the structure of (B), the principal organic product of the foll...

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  20. When a mixture of t-butyl alcohol and and ethyl alcohol is heated with...

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