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An aromatic compound (A), C(7)H(5)NO(2)C...

An aromatic compound (A), `C_(7)H_(5)NO_(2)CI_(2)` on reduction with `Sn//HCI` gives (G), which on reaction with `NaNO_(2)//HCI` gives (B). Compound (B) does not form a dye with `beta`-naphthol. However, (B) gives red colour with ceric ammonium nitrate and on oxidation gives an acid (D) of equivalent weight 191. Decarboxylation of (D) gives (E), which forms a mono nitro derivative (F) on nitrotion. Give the structures of (A) to (F) with proper reasoning.

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To solve the problem step by step, we will analyze the information provided and deduce the structures of compounds (A) to (F). ### Step 1: Determine the structure of compound (A) Given the molecular formula of compound (A) is `C7H5NO2Cl2`, we first calculate the degree of unsaturation. **Degree of Unsaturation Calculation:** Using the formula: \[ \text{Degree of Unsaturation} = \frac{(2n + 2 - n_H - n_X - n_N)}{2} \] ...
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CENGAGE CHEMISTRY ENGLISH-ALCOHOL,PHENOL AND ETHERS-Exercises Subjective
  1. Compound (A), C(8)H(6)NOBr, is optically active. Reduction of (A) give...

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  2. Identify A to E.

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  3. An organic compound (A) (C(8)H(8)O(3)) was insoluble in water, dilute ...

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  4. Neutralisation of 30 gm of a mixture of acetic acid and phenol solutio...

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  5. Find the structure of (A), C(10)H(10)O(2), a sweet-smelling liquid tha...

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  6. a. Isomers (A) and (B), C(10)H(12)O, are isolated form the oil of bay...

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  7. An aromatic compound (A), C(7)H(5)NO(2)CI(2) on reduction with Sn//HCI...

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  8. An organic compound (A) gives opsitive Liebermann reaction and on trea...

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  9. Two isomeric compounds, (A) and (B), have the same formula, C(11)H(13)...

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  10. Nirtobenzene is formed as the major product along with a minor product...

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  11. Identify A, B, and C, in the following reaction.

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  12. Provide a mechanism for the products (A) and (B). Which one will be th...

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  13. Identify the substances (A) through (D) in a sequence. Comment on...

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  14. Identify each of the following glucose derivative. a. A+5HIO(4)rarr...

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  15. If is treated with alkaline NaN(3) and followed by reduction with H(2...

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  16. Converst

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  17. Assign the structure of (B), the principal organic product of the foll...

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  18. When a mixture of t-butyl alcohol and and ethyl alcohol is heated with...

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  19. Identify the major products (B) to (H). a.

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  20. When pent-4-en-1-ol is treated with aqueous Br(2)//O^(-)H, a cyclic b...

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