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While separating a mixture of ortho- and...

While separating a mixture of ortho- and para-nitrophenols steam distillation, name the isomer which will be steam volatile. Give reason.

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To solve the question regarding the steam volatility of ortho- and para-nitrophenols, we need to analyze the molecular structures and the types of hydrogen bonding present in each isomer. ### Step-by-Step Solution: 1. **Identify the Structures of the Isomers**: - Ortho-nitrophenol (o-nitrophenol) has the nitro group (-NO2) and hydroxyl group (-OH) on adjacent carbon atoms of the benzene ring. - Para-nitrophenol (p-nitrophenol) has the nitro group and hydroxyl group on opposite sides of the benzene ring. ...
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CENGAGE CHEMISTRY ENGLISH-ALCOHOL,PHENOL AND ETHERS-Exercises Concept Application
  1. What is meant by hydroboration-oxidation reaction? Illustrate it with ...

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  2. Give the structures and IUPAC names of monohydric phenols of molecular...

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  3. While separating a mixture of ortho- and para-nitrophenols steam disti...

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  4. Give the equations of reactions for the preparation of phenol from cum...

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  5. Write chemical reaction for the preparation of phenol from chlorobenze...

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  6. Write the mechanism of hydration of ethene to yield ethanol.

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  7. You are given benzene, conc. H(2)SO(4) and NaOH. Write the equations ...

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  8. Show how will you synthesise: (i) 1-phenylethanol from a suitable al...

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  9. Give two reactions that show the acidic nature of phenol. Compare acid...

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  10. Explain why is ortho nitrophenol more acidic than ortho methoxyphenol ...

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  11. Explain how does the –OH group attached to a carbon of benzene ring ac...

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  12. Give equations of the following reactions: (i) Oxidation of propan-1...

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  13. Explain the following with an example: i. Kolbe's reaction ii. R...

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  14. Write the mechanism of hydration of ethene to yield ethanol.

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  15. How are the following conversions carried out? (i) Propene rarr Pro...

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  16. Name the reagents used in the following reactions: (i) Oxidation of ...

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  17. Give reason for the higher boiling point of ethanol in comparison to m...

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  18. Give the IUPAC names of the following ethers: C(2)H(5)OCH(2)--overse...

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  19. Write the names of reagents and equations for the preparation of the f...

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  20. Illustrate with examples the limitations of Williamson synthesis for t...

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