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Show how will you synthesise: (i) 1-ph...

Show how will you synthesise:
(i) 1-phenylethanol from a suitable alkene.
(ii) cyclohexylmethanol using an alkyl halide by an `S_(N)2` reaction.
(iii) pentan-1-ol using a suitable alkyl halide?

Text Solution

Verified by Experts

i. Addition of `H_(2)O~ to ethenylbenzene in the pressence of dil. `H_(2)SO_(4)` gives 1-phenylethanol.

ii. Hydrolysis of cyclohexylmethyl bromide by aqueous NaOH gives cyclohexylmethanol.

iii. Hydrolysis of 1-bromopropane by aqueous NaOH gives propan-1-ol.
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CENGAGE CHEMISTRY ENGLISH-ALCOHOL,PHENOL AND ETHERS-Exercises Concept Application
  1. Write the mechanism of hydration of ethene to yield ethanol.

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  2. You are given benzene, conc. H(2)SO(4) and NaOH. Write the equations ...

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  3. Show how will you synthesise: (i) 1-phenylethanol from a suitable al...

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  4. Give two reactions that show the acidic nature of phenol. Compare acid...

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  5. Explain why is ortho nitrophenol more acidic than ortho methoxyphenol ...

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  6. Explain how does the –OH group attached to a carbon of benzene ring ac...

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  7. Give equations of the following reactions: (i) Oxidation of propan-1...

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  8. Explain the following with an example: i. Kolbe's reaction ii. R...

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  9. Write the mechanism of hydration of ethene to yield ethanol.

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  10. How are the following conversions carried out? (i) Propene rarr Pro...

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  11. Name the reagents used in the following reactions: (i) Oxidation of ...

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  12. Give reason for the higher boiling point of ethanol in comparison to m...

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  13. Give the IUPAC names of the following ethers: C(2)H(5)OCH(2)--overse...

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  14. Write the names of reagents and equations for the preparation of the f...

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  15. Illustrate with examples the limitations of Williamson synthesis for t...

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  16. How is 1-propoxypropane synthesised from propan-1-ol? Write mechanism ...

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  17. Preparation of ethers by acid dehydration of secondary or tertiary alc...

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  18. Write the equation of the reaction of hydrogen iodide with: (i) 1-pro...

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  19. Explain the fact that in aryl alkyl ethers (i) the alkoxy group activa...

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  20. Write the mechanism of the reaction of HI with methoxymethane.

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