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How are the following conversions carrie...

How are the following conversions carried out?
(i) Propene `rarr` Propan-2-ol.
(ii) Benzyl chloride `rarr` Benzyl alcohol.
(iii) Ethyl magnesium chloride `rarr` Propan-1-ol.
(iv) Methyl magnesium bromide `rarr` 2-Methylpropan-2-ol.

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i. Propan-2-ol can be prepared form preopene by hydration as shows below:
`CH_(3)`---`overset (CH=CH_(2)) underset (Propene)` + conc. `H_(2)SO_(4) rarr CH_(3)`---`overset (CH---CH_(3)) underset (OSO_(3)H Isopropyl hydrogen sulphate) underset (|)

ii.
iii.
iv.
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CENGAGE CHEMISTRY ENGLISH-ALCOHOL,PHENOL AND ETHERS-Exercises Concept Application
  1. Give two reactions that show the acidic nature of phenol. Compare acid...

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  2. Explain why is ortho nitrophenol more acidic than ortho methoxyphenol ...

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  3. Explain how does the –OH group attached to a carbon of benzene ring ac...

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  4. Give equations of the following reactions: (i) Oxidation of propan-1...

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  5. Explain the following with an example: i. Kolbe's reaction ii. R...

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  6. Write the mechanism of hydration of ethene to yield ethanol.

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  7. How are the following conversions carried out? (i) Propene rarr Pro...

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  8. Name the reagents used in the following reactions: (i) Oxidation of ...

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  9. Give reason for the higher boiling point of ethanol in comparison to m...

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  10. Give the IUPAC names of the following ethers: C(2)H(5)OCH(2)--overse...

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  11. Write the names of reagents and equations for the preparation of the f...

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  12. Illustrate with examples the limitations of Williamson synthesis for t...

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  13. How is 1-propoxypropane synthesised from propan-1-ol? Write mechanism ...

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  14. Preparation of ethers by acid dehydration of secondary or tertiary alc...

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  15. Write the equation of the reaction of hydrogen iodide with: (i) 1-pro...

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  16. Explain the fact that in aryl alkyl ethers (i) the alkoxy group activa...

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  17. Write the mechanism of the reaction of HI with methoxymethane.

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  18. Write equations of the following reactions: (i) Friedel-Crafts react...

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  19. Show how would you synthesise the following alcohols from appropriate ...

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  20. when 3-methylbutan-2-ol is treated with HBr, the following reaction ta...

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