Home
Class 12
CHEMISTRY
Name the reagents used in the following ...

Name the reagents used in the following reactions:
(i) Oxidation of a primary alcohol to carboxylic acid.
(ii) Oxidation of a primary alcohol to aldehyde.
(iii) Bromination of phenol to 2,4,6-tribromophenol.
(iv) Benzyl alcohol to benzoic acid.
(v) Dehydration of propan-2-ol to propene.
(vi) Butan-2-one to butan-2-ol.

Text Solution

Verified by Experts

i. Acidified postassium dichromate or netural, acidic, or alkaline potassium permanganate.
ii. Pyridinium chlorochromate (PCC).
`overset (C_(5)H_(5)N^(o+)HCICrCO_(3)^(-)) underset (dichromate(PDC))`, in `CH_(2)CI_(2)` or Pyridinium
`(C_(5)H_(5)N^(o+)H)_(2)Cr_(2)O_(7)^(2-)` in `CH_(2)CI_(2)` .
iii. Aqueous bromine, i.e., `Br_(2)//H_(2)O`.
iv. Acidifield or alkaline potassium permanganate.
v. Conc. `H_(2)SO_(4)` at `433-443` K or `85%` phosphoric acid at 443K.
vi. `Ni//H_(2)` or `NaBH_(4)` or `LiAIH_(4)`
Promotional Banner

Topper's Solved these Questions

  • ALCOHOL,PHENOL AND ETHERS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Linked Comprehension|60 Videos
  • ALCOHOL,PHENOL AND ETHERS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct|24 Videos
  • ALCOHOL,PHENOL AND ETHERS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Subjective|25 Videos
  • ALIPHATIC AND AROMATIC ALDEHYDES AND KETONES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|26 Videos

Similar Questions

Explore conceptually related problems

Name the reagents used in the following reactions: i. Oxidation of a primary alcohol to carboxylic acid. ii. Oxidation of a primary alchol to aldehyde. iii. Bromination of phenol to 2,4,6-tribromonophenol. iv. Benzyl alcohol to benzoic acid. v. Dehydration of propan-2-ol to propene. vi. Butan-2-one to butan-2-ol.

Name the reagents whch are used in the following conversions : (i) A primary alcohol to an aldehyde (ii) Butan-2-one to butan-2-ol (iii) Phenol to 2, 4, 6-tribromophenol

Write the formula of reagents used in the following reactions: (i) Bromination of phenol to 2, 4,6-tribromophenol (ii) Hydroboration of propene and then oxidation to propanol.

How will you convert (i) Propene to Propan-2-ol? (ii) Phenol to 2,4,6-trinitrophenol ?

Write chemical reactions to affect the following transformations: (i) Butan-1-ol to butanoic acid (ii) Benzyl alcohol to phenylethanoic acid (iii) 3 Nitrobromobenzene to 3-nitrobenzoic acid (iv) 4-Methylacetophenone to benzene-1,4-dicarboxylic acid (v) Cyclohexene to hexane-1,6-dioic acid (vi) Butanal to butanoic acid.

How will you convert the following? (i) Propan - 2 - ol to propanone. (ii) Phenol to 2, 4, 6-tribromophenol.

(a) Give the equations of the following reactions: (i) Oxidation of propan-1-ol with alkaline KMnO_(4) solution. (ii) Propene to propan-2-ol (iii) Benzyl chloride to benzyl alcohol (iv) Ethylmagnesium chloride to propan-1-ol. (b) Write the reactions and their conditions only for the commercial preparation of phenol from cumene.

Give names of the reagents to bring about the following transformations: (i) Hexan-1-ol to hexanal (ii) Cyclohexanol to cyclohexanone (iii) p-Fluorotoluene to (iv) Ethanenitrile to ethanal p-fluorobenzaldehyde (v) Allyl alcohol to propenal (vi) But-2-ene to ethanal

Write chemical equations for the following conversion : (i) Nitrobenzene to benzoic acid. (ii) Benzyl chloride to 2-pheylethanamine . (iii) Aniline to benzyl alcohol.

Write the IUPAC names of the following compounds : (i) t-butyl alcohol (ii) Lactic acid (iii) Isobutyl alcohol (iv) Glycerine (v) Glycine.

CENGAGE CHEMISTRY ENGLISH-ALCOHOL,PHENOL AND ETHERS-Exercises Concept Application
  1. Give two reactions that show the acidic nature of phenol. Compare acid...

    Text Solution

    |

  2. Explain why is ortho nitrophenol more acidic than ortho methoxyphenol ...

    Text Solution

    |

  3. Explain how does the –OH group attached to a carbon of benzene ring ac...

    Text Solution

    |

  4. Give equations of the following reactions: (i) Oxidation of propan-1...

    Text Solution

    |

  5. Explain the following with an example: i. Kolbe's reaction ii. R...

    Text Solution

    |

  6. Write the mechanism of hydration of ethene to yield ethanol.

    Text Solution

    |

  7. How are the following conversions carried out? (i) Propene rarr Pro...

    Text Solution

    |

  8. Name the reagents used in the following reactions: (i) Oxidation of ...

    Text Solution

    |

  9. Give reason for the higher boiling point of ethanol in comparison to m...

    Text Solution

    |

  10. Give the IUPAC names of the following ethers: C(2)H(5)OCH(2)--overse...

    Text Solution

    |

  11. Write the names of reagents and equations for the preparation of the f...

    Text Solution

    |

  12. Illustrate with examples the limitations of Williamson synthesis for t...

    Text Solution

    |

  13. How is 1-propoxypropane synthesised from propan-1-ol? Write mechanism ...

    Text Solution

    |

  14. Preparation of ethers by acid dehydration of secondary or tertiary alc...

    Text Solution

    |

  15. Write the equation of the reaction of hydrogen iodide with: (i) 1-pro...

    Text Solution

    |

  16. Explain the fact that in aryl alkyl ethers (i) the alkoxy group activa...

    Text Solution

    |

  17. Write the mechanism of the reaction of HI with methoxymethane.

    Text Solution

    |

  18. Write equations of the following reactions: (i) Friedel-Crafts react...

    Text Solution

    |

  19. Show how would you synthesise the following alcohols from appropriate ...

    Text Solution

    |

  20. when 3-methylbutan-2-ol is treated with HBr, the following reaction ta...

    Text Solution

    |